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8.1.1 Arrangement of the Periodic Table and periodic trends

How the Periodic Table is arranged

Definition

Periodic Table

An arrangement of all the known elements in order of increasing proton number, set out in periods and groups.

Definition

Proton number

The number of protons in the nucleus of an atom, also known as the atomic number.

Definition

Period

A horizontal row of elements in the Periodic Table whose atoms have the same number of occupied electron shells.

Definition

Group

A vertical column of elements in the Periodic Table whose atoms have the same number of outer-shell electrons.

  1. The Periodic Table places every known element in order of increasing proton number, which is also called the atomic number.
  2. Hydrogen, with one proton in each nucleus, comes first, helium with two protons comes second, and each element after that has one more proton than the element before it.
  3. Every element has its own proton number, so every element has exactly one position in the table.
  4. The horizontal rows are called periods, and they are numbered from Period 1 at the top to Period 7 at the bottom.
  5. The vertical columns are called groups, and the main groups are numbered with Roman numerals from Group I on the far left to Group VIII on the far right.
  6. The block of metals between Group II and Group III contains the transition elements, which are not given a group number in this numbering.
  7. Each box in the table shows the element's symbol, its name, its proton number and its relative atomic mass.
  8. Elements in the same period have the same number of occupied electron shells.
  9. Elements in the same group have the same number of outer-shell electrons.

The Periodic Table, with the elements arranged in order of increasing proton number in Periods 1 to 7 and in groups, showing each element's symbol, proton number and relative atomic mass, with metals on the left and non-metals on the right.

Example

Locating sulfur in the Periodic Table

  • Sulfur has a proton number of 161616, so each sulfur atom contains 161616 protons and 161616 electrons.
  • The electrons fill the shells as 2,8,62,8,62,8,6.
  • Sulfur atoms have three occupied shells, so sulfur is in Period 3.
  • Sulfur atoms have six outer-shell electrons, so sulfur is in Group VI.
  • Phosphorus, with a proton number of 151515, sits immediately to the left of sulfur, and chlorine, with a proton number of 171717, sits immediately to its right.

Metals to non-metals across a period

Definition

Metallic character

The extent to which an element behaves as a metal, shown mainly by how readily its atoms lose electrons to form positive ions.

  1. Moving from left to right across a period, the elements change from metals to non-metals.
  2. In Period 3, sodium, magnesium and aluminium are metals, silicon has properties between those of metals and non-metals, and phosphorus, sulfur, chlorine and argon are non-metals.
  3. Atoms on the left of a period have only one, two or three outer-shell electrons, and they lose these electrons in reactions to form positive ions.
  4. Losing electrons to form positive ions is typical metallic behaviour.
  5. Atoms on the right of a period have nearly full outer shells, so they tend to gain or share electrons instead.
  6. Gaining or sharing electrons is typical non-metallic behaviour.
  7. Metallic character therefore decreases across a period, while non-metallic character increases.
  8. The physical properties follow the same pattern, so the shiny solids that conduct electricity on the left give way to dull solids and gases that do not conduct on the right.
  9. The metals of a period sit to the left of a stepped line that runs down the right-hand side of the table, and the non-metals sit to the right of this line.
Common Mistake
  • Do not write that metallic character increases across a period, because it decreases from left to right while non-metallic character increases.
  • Do not use this pattern to describe a change down a group, because it describes a change along a horizontal row.

Group number and the charge on ions

  1. Atoms form ions by losing or gaining electrons until their outer shell is full, giving them the same electronic configuration as a noble gas.
  2. For Groups I to VII, the group number equals the number of outer-shell electrons, so it tells you how many electrons each atom must lose or gain.
  3. Groups I, II and III: atoms lose their outer-shell electrons and form positive ions.
    1. Group I atoms lose one electron and form ions with a charge of +1+1+1, such as Na+\text{Na}^{+}Na+.
    2. Group II atoms lose two electrons and form ions with a charge of +2+2+2, such as Mg2+\text{Mg}^{2+}Mg2+.
    3. Group III atoms lose three electrons and form ions with a charge of +3+3+3, such as Al3+\text{Al}^{3+}Al3+.
  4. Groups V, VI and VII: atoms gain electrons to fill their outer shell and form negative ions.
    1. Group V atoms gain three electrons and form ions with a charge of −3-3−3, such as N3−\text{N}^{3-}N3−.
    2. Group VI atoms gain two electrons and form ions with a charge of −2-2−2, such as O2−\text{O}^{2-}O2−.
    3. Group VII atoms gain one electron and form ions with a charge of −1-1−1, such as Cl−\text{Cl}^{-}Cl−.
  5. For Groups I to III, the size of the positive charge equals the group number.
  6. For Groups V to VII, the size of the negative charge equals eight minus the group number.
  7. Group IV atoms such as carbon and silicon would have to lose or gain four electrons, so they usually share electrons in covalent bonds and do not form simple ions.
  8. Group VIII atoms already have a full outer shell, so they do not form ions at all.
Example

Predicting the ions of calcium and sulfur

  • Calcium is in Group II, so each calcium atom loses its two outer-shell electrons.

Ca→Ca2++2e−\text{Ca} \rightarrow \text{Ca}^{2+} + 2e^{-}Ca→Ca2++2e−

  • The calcium ion has the electronic configuration 2,8,82,8,82,8,8, which is the same as argon.
  • Sulfur is in Group VI, so each sulfur atom gains two electrons to fill its outer shell.

S+2e−→S2−\text{S} + 2e^{-} \rightarrow \text{S}^{2-}S+2e−→S2−

  • The sulfide ion also has the electronic configuration 2,8,82,8,82,8,8.
  • Calcium sulfide therefore has the formula CaS\text{CaS}CaS, because one Ca2+\text{Ca}^{2+}Ca2+ ion balances the charge of one S2−\text{S}^{2-}S2− ion.

Similar properties within a group

Definition

Electronic configuration

The arrangement of electrons in the shells of an atom or ion, written as the number of electrons in each shell starting from the shell nearest the nucleus.

  1. Elements in the same group have the same number of electrons in their outer shell.
  2. Lithium (2,12,12,1), sodium (2,8,12,8,12,8,1) and potassium (2,8,8,12,8,8,12,8,8,1) each have one outer-shell electron.
  3. Fluorine (2,72,72,7) and chlorine (2,8,72,8,72,8,7) each have seven outer-shell electrons.
  4. In a chemical reaction, it is the outer-shell electrons that are lost, gained or shared.
  5. Atoms with the same number of outer-shell electrons therefore react in the same way, so elements in the same group have similar chemical properties.
  6. They form ions with the same charge, so sodium and potassium both form +1+1+1 ions.
  7. They also form compounds with the same type of formula, so sodium chloride is NaCl\text{NaCl}NaCl and potassium chloride is KCl\text{KCl}KCl.
  8. The properties are similar rather than identical, because each element further down a group has one more occupied shell than the element above it.
  9. This extra shell produces gradual changes in properties down a group, such as a steady change in reactivity.
Exam technique

Explaining similar chemical properties

  • Give the reason as the same number of outer-shell electrons or the same number of electrons in the outer shell.
  • Writing "the same number of electrons" or "the same number of shells" does not earn the mark, because elements in a group have different total numbers of electrons and different numbers of shells.
  • Add that reactions involve the outer-shell electrons, so atoms with the same outer shell react in the same way.

Predicting properties from position

  1. Period number: this tells you the number of occupied electron shells in an atom of the element.
  2. Group number: this tells you the number of outer-shell electrons for Groups I to VII.
    1. From the outer-shell electrons you can predict the charge on the ion the element forms.
    2. You can also predict that the element reacts in a similar way to the other members of its group.
  3. Position across the period: this tells you whether the element is likely to be a metal or a non-metal.
    1. An element towards the left of a period is likely to be a metal that forms positive ions.
    2. An element towards the right of a period is likely to be a non-metal that forms negative ions or shares electrons.
  4. Known members of the same group: an unfamiliar element is expected to behave like the elements above and below it, with its properties continuing the pattern down the group.
Example

Predicting the properties of strontium

  • Strontium is in Period 5 and Group II.
  • Being in Period 5, a strontium atom has five occupied electron shells.
  • Being in Group II, a strontium atom has two outer-shell electrons.
  • Strontium is on the left of its period, so it is a metal.
  • Each strontium atom loses two electrons to form an Sr2+\text{Sr}^{2+}Sr2+ ion.
  • Strontium reacts in a similar way to magnesium and calcium, which are also in Group II.
  • Strontium chloride has the formula SrCl2\text{SrCl}_2SrCl2​, matching magnesium chloride, MgCl2\text{MgCl}_2MgCl2​.
Self review
  • In what order are the elements arranged in the Periodic Table?
  • What is the difference between a period and a group?
  • How does metallic character change from left to right across a period?
  • What charge is on the ions formed by elements in Group II, Group III and Group VI?
  • Why do elements in the same group have similar chemical properties?
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8.1.1 Arrangement of the Periodic Table and periodic trends Revision Guide

  1. IGCSE
  2. /Chemistry
  3. /8.1.1 Arrangement of the Periodic Table and periodic trends

Revision notes for CIE IGCSE Chemistry 8.1.1 Arrangement of the Periodic Table and periodic trends: explanations and worked examples.

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