Proton and mass numbers describe a nucleus
Definition
Atomic number
The number of protons in the nucleus of an atom.
- The atomic number, also called the proton number, identifies the element because every atom of one element has the same number of protons.
- A nucleus containing six protons is carbon, and its positive nuclear charge is +6+6+6 in relative units.
Definition
Mass number
The total number of protons and neutrons in the nucleus of an atom.
- The mass number, also called the nucleon number, counts all nucleons in the nucleus.
- The relationship is A=Z+NA=Z+NA=Z+N, where AAA is mass number, ZZZ is atomic number and NNN is number of neutrons.
- Rearranging gives N=A−ZN=A-ZN=A−Z.
Isotopes share protons but differ in neutrons
Definition
Isotopes
Atoms of the same element with the same number of protons but different numbers of neutrons.
- Isotopes have the same atomic number and the same positive nuclear charge because they contain the same number of protons.
- They have different mass numbers because their nuclei contain different numbers of neutrons.
- Changing the neutron number makes a different isotope, while changing the proton number makes a different element.
- Carbon-12 has six protons and six neutrons, while carbon-13 has six protons and seven neutrons.
Common Mistake
- Do not say that isotopes have different proton numbers; atoms with different proton numbers are different elements.
- Do not use mass number as the number of neutrons; it is the total number of protons and neutrons.
Nuclear notation places both numbers on the left
- An isotope is written as ZAX{}^{A}_{Z}\mathrm{X}ZAX, where X\mathrm{X}X is the element symbol.
- The mass number AAA is the upper-left number and the atomic number ZZZ is the lower-left number.
- For carbon-13, 613C{}^{13}_{6}\mathrm{C}613C shows thirteen nucleons in total and six protons.
Example
Reading a nuclear symbol
- For 1123Na{}^{23}_{11}\mathrm{Na}1123Na, the atomic number gives 111111 protons.
- The neutron number is N=A−Z=23−11=12N=A-Z=23-11=12N=A−Z=23−11=12.
- A neutral sodium-23 atom also has 111111 electrons.
Comparisons must name both similarities and differences
- Two nuclei are isotopes when their lower-left numbers are equal and their upper-left numbers are different.
- A full explanation states that they have the same number of protons but different numbers of neutrons.
Exam technique
Explaining isotope notation
- Read the lower-left number first to identify the element, then subtract it from the upper-left number to find the neutron number.
- When comparing isotopes, give both required links: same proton number and different neutron number.
Self review
- What does atomic number count?
- What does mass number count?
- How do you calculate neutron number?
- Why do isotopes have the same nuclear charge?
- What do AAA, ZZZ and X\mathrm{X}X represent in ZAX{}^{A}_{Z}\mathrm{X}ZAX?