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6.1.2 Isotopes: atomic and mass number

Proton and mass numbers describe a nucleus

Definition

Atomic number

The number of protons in the nucleus of an atom.

  1. The atomic number, also called the proton number, identifies the element because every atom of one element has the same number of protons.
  2. A nucleus containing six protons is carbon, and its positive nuclear charge is +6+6+6 in relative units.
Definition

Mass number

The total number of protons and neutrons in the nucleus of an atom.

  1. The mass number, also called the nucleon number, counts all nucleons in the nucleus.
  2. The relationship is A=Z+NA=Z+NA=Z+N, where AAA is mass number, ZZZ is atomic number and NNN is number of neutrons.
  3. Rearranging gives N=A−ZN=A-ZN=A−Z.

Isotopes share protons but differ in neutrons

Definition

Isotopes

Atoms of the same element with the same number of protons but different numbers of neutrons.

  1. Isotopes have the same atomic number and the same positive nuclear charge because they contain the same number of protons.
  2. They have different mass numbers because their nuclei contain different numbers of neutrons.
  3. Changing the neutron number makes a different isotope, while changing the proton number makes a different element.
  4. Carbon-12 has six protons and six neutrons, while carbon-13 has six protons and seven neutrons.
Common Mistake
  • Do not say that isotopes have different proton numbers; atoms with different proton numbers are different elements.
  • Do not use mass number as the number of neutrons; it is the total number of protons and neutrons.

Nuclear notation places both numbers on the left

  1. An isotope is written as ZAX{}^{A}_{Z}\mathrm{X}ZA​X, where X\mathrm{X}X is the element symbol.
  2. The mass number AAA is the upper-left number and the atomic number ZZZ is the lower-left number.
  3. For carbon-13, 613C{}^{13}_{6}\mathrm{C}613​C shows thirteen nucleons in total and six protons.
Example

Reading a nuclear symbol

  • For 1123Na{}^{23}_{11}\mathrm{Na}1123​Na, the atomic number gives 111111 protons.
  • The neutron number is N=A−Z=23−11=12N=A-Z=23-11=12N=A−Z=23−11=12.
  • A neutral sodium-23 atom also has 111111 electrons.

Comparisons must name both similarities and differences

  1. Two nuclei are isotopes when their lower-left numbers are equal and their upper-left numbers are different.
  2. A full explanation states that they have the same number of protons but different numbers of neutrons.
Exam technique

Explaining isotope notation

  • Read the lower-left number first to identify the element, then subtract it from the upper-left number to find the neutron number.
  • When comparing isotopes, give both required links: same proton number and different neutron number.
Self review
  • What does atomic number count?
  • What does mass number count?
  • How do you calculate neutron number?
  • Why do isotopes have the same nuclear charge?
  • What do AAA, ZZZ and X\mathrm{X}X represent in ZAX{}^{A}_{Z}\mathrm{X}ZA​X?
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6.1.2 Isotopes: atomic and mass number Revision Guide

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  2. /Physics
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Revision notes for Edexcel GCSE Physics 6.1.2 Isotopes: atomic and mass number: explanations and worked examples.

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