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5.1.5 Resistance to oxidation and recycling metals

5.1.5 Resistance to oxidation and recycling metals

Resistance to oxidation follows the reactivity series

Definition

Oxidation

The loss of electrons by a substance.

  1. A metal reacts with the oxygen in air to form its oxide, which is an oxidation.
  2. A metal high in the reactivity series is oxidised quickly, because its atoms lose electrons readily.
  3. Potassium and sodium tarnish within seconds of being cut, so they are stored under oil.
  4. Iron and zinc are oxidised slowly in moist air over weeks and months.
  5. Gold and platinum are not oxidised in air at all, which is why they keep their shine.
Key Idea

Resistance to oxidation runs opposite to reactivity, so the least reactive metals last the longest in air.

Aluminium behaves better than its position suggests

  1. Aluminium sits above zinc and iron, so it would be expected to corrode faster than either.
  2. In practice aluminium objects last for years without visibly corroding.
  3. The metal reacts at once with air to form a thin layer of aluminium oxide.
  4. That layer sticks firmly to the surface and seals the metal underneath from further attack.
  5. The oxide layer, not low reactivity, is what makes aluminium useful outdoors.
Note
  • The layer re-forms if the surface is scratched, so the protection is self-repairing.
  • Iron's oxide flakes away instead of sealing, which is why iron keeps on rusting.

Recycling returns a used metal to service

Definition

Recycling

Processing a used material so that it can be made into a new product instead of being thrown away.

  1. A used metal object is collected, sorted, melted and cast into new stock.
  2. The metal is an element, so it is not used up and can be recycled many times over.
  3. Recycling skips mining, transport and reduction of the ore entirely.
  4. Recycling aluminium uses only a small fraction of the energy that electrolysis of its ore demands.
  5. Each tonne recycled leaves a tonne of ore in the ground for later use.
Example
  • Aluminium drinks cans are melted and rolled into new sheet, avoiding the electrolysis step.
  • Scrap steel is added to a furnace charge, which cuts both the ore and the energy needed.

The case for recycling is economic as well as environmental

  1. Less energy is bought, so the running cost per tonne of metal is usually lower.
  2. Less ore is mined, which limits habitat damage and the waste rock left behind.
  3. Fewer fossil fuels are burned, so less carbon dioxide reaches the atmosphere.
  4. Less metal is sent to landfill, where it takes up space and can leach into the ground.
  5. A reserve of ore is a finite raw material, so using less of it protects future supply.
Common Mistake
  • Recycling is not free: collecting and sorting scrap costs money and energy of its own.
  • Mixed or heavily contaminated scrap can cost more to separate than the metal it yields.

Judging the evidence on recycling a particular metal

  1. The saving is largest where extraction is most expensive, which is why aluminium is the clearest case.
  2. For a cheaply extracted metal the saving is smaller, though it still exists.
  3. The quality of the recycled metal matters, since some scrap is only fit for lower-grade uses.
  4. Distance counts, because transporting scrap a long way uses fuel that eats into the saving.
  5. A sound judgement compares energy, cost and supply together rather than any one of them alone.
Self review
  • Why is gold still shiny after centuries in air?
  • Why does aluminium resist corrosion better than its position in the reactivity series suggests?
  • Give two environmental advantages of recycling a metal.
  • Why is the saving from recycling greatest for aluminium?
  • Give one reason why recycling a metal may not be worthwhile.
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Oxidation is the loss of electrons by a substance. When a metal reacts with oxygen in air to form a metal oxide, the metal has been oxidised.

A metal high in the reactivity series loses electrons readily, so it is oxidised quickly. Resistance to oxidation therefore increases as reactivity decreases.

Potassium and sodium tarnish within seconds of being cut and are stored under oil. Iron and zinc oxidise slowly in moist air, while gold and platinum are not oxidised in air and keep their shine.

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Why are metals high in the reactivity series oxidised quickly?

5.1.5 Resistance to oxidation and recycling metals Revision Guide

  1. GCSE
  2. /Chemistry
  3. /5.1.5 Resistance to oxidation and recycling metals

Revision notes for Edexcel GCSE Chemistry 5.1.5 Resistance to oxidation and recycling metals: explanations and worked examples.

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