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10.5.1 Nanoparticles: size, uses and risks

Nanoparticles sit between atoms and everyday particles

Definition

Nanoparticle

A particle between about 1 and 100 nanometres across, which is far larger than an atom but far smaller than a speck of dust.

  1. A nanoparticle measures between about 111 and 100100100 nanometres across.
  2. A single atom is roughly a tenth of a nanometre across.
  3. A nanoparticle therefore holds anything from a few tens of atoms to many millions.
  4. It is far larger than an atom or a small molecule, though a large molecule such as a protein reaches this size.
  5. It is far smaller than anything visible, including a speck of dust.
Key Idea

Nanoparticles occupy a gap in scale: far larger than ordinary molecules, yet too small to behave like bulk material.

A large surface area to volume ratio changes behaviour

Definition

Surface area to volume ratio

The surface area of a solid compared with its volume, which increases as the solid is broken into smaller pieces.

  1. Dividing a solid into smaller pieces raises its surface area to volume ratio.
  2. At nanoparticle size, that ratio becomes very large.
  3. A large proportion of the atoms therefore sits at the surface.
  4. Reactions happen at surfaces, so nanoparticles are far more reactive than the bulk material.
  5. A much smaller mass can therefore do the same job.
Example
  • Bulk solid: almost all of its atoms are buried inside.
  • Nanoparticles: a large share of the atoms are exposed at the surface.

Uses that depend on that behaviour

  1. Sunscreens use nanoparticles of titanium dioxide or zinc oxide.
  2. The particles block ultraviolet light while being too small to look white on the skin.
  3. An older sunscreen using the bulk powder left a visible white layer.
  4. Nanoparticle catalysts work with a much smaller mass of expensive metal.
  5. Other uses include self-cleaning surfaces and stronger, lighter materials.
Note

The sunscreen still blocks the same ultraviolet light: only its appearance on the skin has changed.

The possible risks

  1. Some may be able to pass through the skin, and they are small enough to be breathed deep into the lungs.
  2. Their high reactivity may cause effects that the bulk material does not.
  3. The long-term effects on health are not yet fully known.
  4. Particles washed off into rivers and the sea may affect wildlife.
  5. Risk depends on which material the particles are made of, so a result for one says little about another.
Self review
  • What size range counts as a nanoparticle?
  • How does a nanoparticle compare in size with an atom?
  • Why does a large surface area to volume ratio make nanoparticles more reactive?
  • Why are nanoparticles used in sunscreens?
  • Give two possible risks of using nanoparticles.
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Size scale from an atom to a nanoparticle and dust, with a surface-area comparison between a bulk solid and many nanoparticles

A nanoparticle is a particle between about 111 and 100 nm100 \, \text{nm}100nm across. An atom is roughly 0.1 nm0.1 \, \text{nm}0.1nm across, so a nanoparticle is far larger than an atom but far smaller than a speck of dust.

A nanoparticle may contain anything from a few tens of atoms to many millions of atoms. Large molecules such as proteins can reach a similar size, but most ordinary molecules are much smaller.

Nanoparticles occupy a special gap in scale: they are too small to behave exactly like bulk material, but they are much larger than individual atoms and small molecules.

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What size range counts as a nanoparticle?

10.5.1 Nanoparticles: size, uses and risks Revision Guide

  1. GCSE
  2. /Chemistry
  3. /10.5.1 Nanoparticles: size, uses and risks

Revision notes for Edexcel GCSE Chemistry 10.5.1 Nanoparticles: size, uses and risks: explanations and worked examples.

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