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2.4.1 Covalent bonding and simple molecules

2.4.1 Covalent bonding and simple molecules

A covalent bond is a shared pair of electrons

Definition

Covalent bond

A shared pair of electrons between two atoms, attracted to the nucleus of each.

Definition

Molecule

A particle made of two or more atoms joined together by covalent bonds.

  1. Two non-metal atoms can each contribute one electron to a pair that sits between them.
  2. Both nuclei attract that shared pair, and that shared attraction is what holds the atoms together.
  3. Neither atom loses an electron outright, so no ions are formed.
  4. Each atom counts the whole shared pair towards its own outer shell.
  5. One shared pair makes one covalent bond, and two shared pairs between the same atoms make a double bond.
  6. Atoms joined this way form particles with a fixed number of atoms, unlike the open-ended ionic lattice.
Key Idea
  • One shared pair makes one covalent bond.
  • Sharing completes both outer shells at once, which is why the atoms stay joined.

Atoms and small molecules are about 10−10 m10^{-10}\ \text{m}10−10 m across

  1. A typical atom measures roughly 10−10 m10^{-10}\ \text{m}10−10 m across.
  2. A small molecule such as H2O\text{H}_2\text{O}H2​O is only a few times wider, so it shares the same order of magnitude.
  3. An order of magnitude is the nearest power of ten, which is all the precision these sizes are quoted to.
  4. The unit is the metre, so 10−10 cm10^{-10}\ \text{cm}10−10 cm is a hundred times too small.
  5. That scale is why single molecules cannot be seen through a light microscope.
Note
  • 10−10 m10^{-10}\ \text{m}10−10 m is the same as 0.10.10.1 nanometres, which is a useful cross-check on a converted answer.
  • A giant covalent structure has no such size, because it is not built from separate molecules.

Dot-and-cross diagrams show shared pairs and lone pairs

Definition

Lone pair

A pair of outer-shell electrons that is not shared between two atoms and so forms no covalent bond.

  1. A dot-and-cross diagram draws only the outer-shell electrons of each atom.
  2. Dots mark the electrons of one atom and crosses those of the other, so each shared pair shows one of each.
  3. A shared pair is drawn in the overlap between the two atoms.
  4. Outer electrons that are not shared stay on their own atom, drawn as pairs.
  5. Those unshared pairs form no bond, so they are not counted when the bonds are counted.
  6. Two shared pairs drawn between the same two atoms represent a double covalent bond.
Common Mistake
  • A lone pair is not a bond, so it never counts towards the number of covalent bonds in a molecule.
  • Both electrons of a shared pair go in the overlap, one dot and one cross, never both on one side.

Single bonds: H2\text{H}_2H2​, HCl\text{HCl}HCl, H2O\text{H}_2\text{O}H2​O and CH4\text{CH}_4CH4​

  1. H2\text{H}_2H2​: each hydrogen contributes its one electron to a single shared pair, leaving both atoms with two electrons and no lone pairs.
  2. HCl\text{HCl}HCl: hydrogen and chlorine share one pair, and chlorine's six remaining outer electrons stay as three lone pairs.
  3. H2O\text{H}_2\text{O}H2​O: oxygen forms a shared pair with each of two hydrogen atoms and keeps four electrons as two lone pairs.

Lewis structure of a water molecule, showing a central oxygen atom bonded to two hydrogen atoms with two lone pairs of electrons on the oxygen atom.

  1. CH4\text{CH}_4CH4​: carbon forms a shared pair with each of four hydrogen atoms and keeps no lone pairs.
  2. Hydrogen is full at two electrons, while chlorine, oxygen and carbon are full at eight.
  3. Counting the shared pairs against the formula is the quickest check that a diagram is complete.
Example
  • Water: two shared pairs plus two lone pairs give oxygen eight outer electrons, and each hydrogen has two.
  • Methane: four shared pairs give carbon eight outer electrons, and each hydrogen has two.

Double bonds: O2\text{O}_2O2​ and CO2\text{CO}_2CO2​

  1. O2\text{O}_2O2​: the two oxygen atoms share two pairs with each other, which makes one double bond.
  2. Each oxygen atom in O2\text{O}_2O2​ keeps two lone pairs, so each reaches eight outer electrons.
  3. CO2\text{CO}_2CO2​: carbon shares two pairs with each oxygen atom, making two double bonds.
  4. Carbon dioxide therefore holds four shared pairs altogether, and carbon keeps no lone pairs.
  5. Each oxygen atom in CO2\text{CO}_2CO2​ keeps two lone pairs.

Lewis structure of a carbon dioxide molecule, showing a central carbon atom double-bonded to two oxygen atoms, with two lone pairs of electrons on each oxygen atom.

  1. A double bond is drawn as two separate shared pairs in the overlap, not as one crowded group.
Note
  • Counting outer-shell electrons first settles how many pairs each atom has to share.
  • Brackets and charges belong to ionic diagrams, so they have no place on a covalent one.

Checking a covalent diagram

  1. Start from the outer-shell electron counts: hydrogen 111, carbon 444, oxygen 666 and chlorine 777.
  2. Work out how many electrons each atom has to share to fill its outer shell.
  3. Draw the shared pairs first, then place the leftover electrons as lone pairs.
  4. Check the totals: two electrons around each hydrogen and eight around each of the others.
  5. Check that the number of atom symbols matches the molecular formula.
Self review
  • What is formed when two atoms share a pair of electrons?
  • What is the typical order of magnitude of the size of an atom or a small molecule?
  • How many lone pairs are drawn on the oxygen atom in H2O\text{H}_2\text{O}H2​O?
  • How many shared pairs lie between carbon and each oxygen atom in CO2\text{CO}_2CO2​?
  • Why does a lone pair not count as a covalent bond?
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A covalent bond is a shared pair of electrons between two non-metal atoms. The shared pair is attracted to the nucleus of both atoms, and this attraction holds the atoms together.

Neither atom loses an electron completely, so covalent bonding does not form ions. Each atom counts the shared pair towards its own outer shell.

One shared pair makes one covalent bond. A molecule is a particle made of two or more atoms joined by covalent bonds, such as H2\text{H}_2H2​, H2O\text{H}_2\text{O}H2​O and CH4\text{CH}_4CH4​.

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What forms when two non-metal atoms share a pair of electrons?

2.4.1 Covalent bonding and simple molecules Revision Guide

  1. GCSE
  2. /Chemistry
  3. /2.4.1 Covalent bonding and simple molecules

Revision notes for Edexcel GCSE Chemistry 2.4.1 Covalent bonding and simple molecules: explanations and worked examples.

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