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9.1.4 Complete and incomplete combustion

9.1.4 Complete and incomplete combustion

Complete combustion gives carbon dioxide and water

Definition

Complete combustion

Burning in a plentiful supply of oxygen, which gives carbon dioxide and water.

  1. Burning a hydrocarbon in a plentiful supply of oxygen is complete combustion.
  2. Every carbon atom ends up in carbon dioxide and every hydrogen atom in water.
  3. The general pattern is: hydrocarbon+oxygen→carbon dioxide+water\text{hydrocarbon} + \text{oxygen} \rightarrow \text{carbon dioxide} + \text{water}hydrocarbon+oxygen→carbon dioxide+water
  4. Methane burning completely gives: CH4+2O2→CO2+2H2O\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}CH4​+2O2​→CO2​+2H2​O
  5. Energy is given out, which is the reason hydrocarbons are burned at all.
Key Idea

Complete combustion releases the most energy and gives the cleanest products.

Incomplete combustion happens in a limited supply of oxygen

Definition

Incomplete combustion

Burning in a limited supply of oxygen, which can give carbon monoxide and carbon as well as water.

  1. With too little oxygen there is not enough to convert every carbon atom fully.
  2. Some carbon is only partly oxidised, giving carbon monoxide, CO\text{CO}CO.
  3. Some carbon is not oxidised at all, and appears as soot.
  4. Water is still formed, because hydrogen is oxidised first.
  5. Less energy is released than from complete combustion of the same fuel.
Example
  • Plenty of air: a blue flame, giving carbon dioxide and water.
  • Limited air: a yellow, smoky flame, giving carbon monoxide and soot as well.

Carbon monoxide is toxic

  1. Carbon monoxide is colourless and odourless, so it gives no warning of its presence.
  2. Breathed in, it binds to the haemoglobin in red blood cells.
  3. Haemoglobin that has bound carbon monoxide can no longer carry oxygen.
  4. The blood therefore delivers less oxygen to the body's cells.
  5. The effects range from headache and drowsiness to unconsciousness and death.
Common Mistake

The danger is that carbon monoxide cannot be detected by smell, which is why alarms are fitted.

Problems caused in appliances that burn fuels

  1. A boiler or heater starved of air produces carbon monoxide indoors.
  2. Soot builds up inside the appliance and in the flue.
  3. A soot deposit blocks the airway, which makes the oxygen supply worse still.
  4. Soot that glows in the flame makes it yellow, which is a visible warning sign.
  5. Regular servicing keeps the air supply clear and the combustion complete.
Note

A yellow, sooty flame on a gas appliance signals incomplete combustion and needs attention.

Self review
  • Write the general word equation for the complete combustion of a hydrocarbon.
  • Why does incomplete combustion produce carbon monoxide and soot?
  • How does carbon monoxide harm the body?
  • Why is carbon monoxide particularly dangerous?
  • What does a yellow, smoky flame on a gas appliance indicate?
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Flowchart comparing complete and incomplete combustion products, flame colours, energy release, and carbon monoxide hazard

Combustion is the burning of a fuel in oxygen. For a hydrocarbon, the amount of oxygen available determines whether combustion is complete or incomplete.

Complete combustion happens in a plentiful supply of oxygen. It produces carbon dioxide and water.

Incomplete combustion happens in a limited supply of oxygen. It can produce carbon monoxide, soot, and water.

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What oxygen supply is needed for complete combustion?

9.1.4 Complete and incomplete combustion Revision Guide

  1. GCSE
  2. /Chemistry
  3. /9.1.4 Complete and incomplete combustion

Revision notes for Edexcel GCSE Chemistry 9.1.4 Complete and incomplete combustion: explanations and worked examples.

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