Complete combustion gives carbon dioxide and water
Complete combustion
Burning in a plentiful supply of oxygen, which gives carbon dioxide and water.
- Burning a hydrocarbon in a plentiful supply of oxygen is complete combustion.
- Every carbon atom ends up in carbon dioxide and every hydrogen atom in water.
- The general pattern is: hydrocarbon+oxygen→carbon dioxide+water\text{hydrocarbon} + \text{oxygen} \rightarrow \text{carbon dioxide} + \text{water}hydrocarbon+oxygen→carbon dioxide+water
- Methane burning completely gives: CH4+2O2→CO2+2H2O\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}CH4+2O2→CO2+2H2O
- Energy is given out, which is the reason hydrocarbons are burned at all.
Complete combustion releases the most energy and gives the cleanest products.
Incomplete combustion happens in a limited supply of oxygen
Incomplete combustion
Burning in a limited supply of oxygen, which can give carbon monoxide and carbon as well as water.
- With too little oxygen there is not enough to convert every carbon atom fully.
- Some carbon is only partly oxidised, giving carbon monoxide, CO\text{CO}CO.
- Some carbon is not oxidised at all, and appears as soot.
- Water is still formed, because hydrogen is oxidised first.
- Less energy is released than from complete combustion of the same fuel.
- Plenty of air: a blue flame, giving carbon dioxide and water.
- Limited air: a yellow, smoky flame, giving carbon monoxide and soot as well.
Carbon monoxide is toxic
- Carbon monoxide is colourless and odourless, so it gives no warning of its presence.
- Breathed in, it binds to the haemoglobin in red blood cells.
- Haemoglobin that has bound carbon monoxide can no longer carry oxygen.
- The blood therefore delivers less oxygen to the body's cells.
- The effects range from headache and drowsiness to unconsciousness and death.
The danger is that carbon monoxide cannot be detected by smell, which is why alarms are fitted.
Problems caused in appliances that burn fuels
- A boiler or heater starved of air produces carbon monoxide indoors.
- Soot builds up inside the appliance and in the flue.
- A soot deposit blocks the airway, which makes the oxygen supply worse still.
- Soot that glows in the flame makes it yellow, which is a visible warning sign.
- Regular servicing keeps the air supply clear and the combustion complete.
A yellow, sooty flame on a gas appliance signals incomplete combustion and needs attention.
- Write the general word equation for the complete combustion of a hydrocarbon.
- Why does incomplete combustion produce carbon monoxide and soot?
- How does carbon monoxide harm the body?
- Why is carbon monoxide particularly dangerous?
- What does a yellow, smoky flame on a gas appliance indicate?
