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7.1.1 Classifying elements by group in the periodic table

7.1.1 Classifying elements by group in the periodic table

A group collects elements that behave alike

Definition

Group

A vertical column of the periodic table, whose elements have the same number of outer-shell electrons and so have similar chemical properties.

Definition

Periodic table

A chart of all the elements arranged in order of increasing atomic number, so that elements with similar properties fall in the same column.

  1. Elements in the same group are placed together because they react in similar ways.
  2. Every element in a main group has the same number of electrons in its outer shell.
  3. That shared outer arrangement is what makes their chemistry similar.
  4. For the main groups the group number gives that count, except for Group 0.
  5. Three groups have names of their own: Group 1, Group 7 and Group 0.
Key Idea

Position in the table is not a label applied afterwards: it predicts how an element will react.

Group 1 elements are the alkali metals

Definition

Alkali metal

An element in Group 1 of the periodic table, which has one electron in its outer shell.

  1. The alkali metals make up Group 1, and include lithium, sodium and potassium.
  2. Each has one electron in its outer shell.
  3. Losing that single electron leaves an ion with a charge of 1+1+1+.
  4. They are metals, so they are shiny when freshly cut and conduct electricity.
  5. Hydrogen sits above them in many layouts but is a non-metal and is not an alkali metal.
Note

The name comes from the alkaline solutions these metals give when they react with water.

Group 7 elements are the halogens

Definition

Halogen

An element in Group 7 of the periodic table, which has seven electrons in its outer shell.

  1. The halogens make up Group 7, and include chlorine, bromine and iodine.
  2. Each has seven electrons in its outer shell.
  3. Gaining one electron completes the shell and gives an ion with a charge of 1−1-1−.
  4. They are non-metals, and they exist as molecules of two atoms such as Cl2\text{Cl}_2Cl2​.
  5. Their compounds with metals are called halides, as in sodium chloride.
Example
  • Chlorine: seven outer electrons, forms Cl−\text{Cl}^{-}Cl−.
  • Sodium: one outer electron, forms Na+\text{Na}^{+}Na+.
  • Together: the two ions give sodium chloride, NaCl\text{NaCl}NaCl.

Group 0 elements are the noble gases

Definition

Noble gas

An element in Group 0 of the periodic table, which has a full outer shell of electrons.

  1. The noble gases make up Group 0, and include helium, neon and argon.
  2. Each has a full outer shell, which is eight electrons for every one except helium.
  3. Helium is full with two electrons, because the first shell holds only two.
  4. Having a full shell means there is nothing to gain, lose or share, so they barely react.
  5. The group number 000 reflects that they form no ordinary compounds, not that they have no outer electrons.
Common Mistake

Group 000 is the one place where the group number does not give the count of outer electrons.

The electronic configuration places an element in its group

Definition

Electronic configuration

The arrangement of an atom's electrons in its shells, written as the number in each shell from the innermost outwards.

  1. Writing out the electron arrangement shows how many electrons occupy the outer shell.
  2. Sodium is 2,8,12,8,12,8,1, so its single outer electron places it in Group 1.
  3. Chlorine is 2,8,72,8,72,8,7, so its seven outer electrons place it in Group 7.
  4. Argon is 2,8,82,8,82,8,8, so its full outer shell places it in Group 0.
  5. Two elements with the same outer count sit in the same group however many inner shells they have.
Self review
  • What do all the elements in a group have in common?
  • How many outer electrons does a halogen atom have?
  • Why is helium a noble gas when it has only two outer electrons?
  • Which group does an element with the configuration 2,8,12,8,12,8,1 belong to?
  • Why does the group number not give the outer electron count for Group 0?
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Simplified periodic table showing Groups 1, 7 and 0, with electron-shell examples for sodium, chlorine and argon

A group is a vertical column in the periodic table. Elements in the same main group have the same number of electrons in their outer shell, so they often have similar chemical properties.

For main-group elements, the group number usually tells you the number of outer-shell electrons. Group 0 is the exception because its atoms have full outer shells rather than zero electrons.

The position of an element therefore helps predict how it reacts. The three named groups are Group 1, the alkali metals; Group 7, the halogens; and Group 0, the noble gases.

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Group 1 elements are called the [     ].

7.1.1 Classifying elements by group in the periodic table Revision Guide

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Revision notes for Edexcel GCSE Chemistry 7.1.1 Classifying elements by group in the periodic table: explanations and worked examples.

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