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2.1.4 Calculating relative atomic mass from isotopic abundance

2.1.4 Calculating relative atomic mass from isotopic abundance

The two numbers a question gives you

Definition

Relative atomic mass

The weighted mean mass of an element's atoms, taking the abundance of each isotope into account, compared with one-twelfth of the mass of a carbon-12 atom.

Definition

Relative isotopic mass

The mass of one isotope compared with one-twelfth of the mass of a carbon-12 atom, which is equal to that isotope's mass number.

Definition

Isotopic abundance

The proportion of the atoms in a sample of an element that are a particular isotope, given as a percentage or a fraction.

  1. A question supplies the mass of each isotope and how common that isotope is.
  2. An isotope's relative isotopic mass is the same number as its mass number.
  3. Abundance may be given as a percentage, as a decimal fraction, or as a count of atoms detected.
  4. The more abundant isotope pulls the average towards its own mass.
  5. Relative atomic mass has no unit, because it compares one mass with another.

A mass spectrum of chlorine showing two peaks. The peak at a mass/charge ratio of 35 has a percentage abundance of 75.8%, and the peak at 37 has a percentage abundance of 24.2%.

Key Idea
  • The answer always lies between the smallest and the largest isotopic mass.
  • It lands nearer the mass of the most abundant isotope.

The method: multiply, add, then divide by the total abundance

  1. Write each isotopic mass and its abundance side by side before calculating anything.
  2. Multiply each isotopic mass by its own abundance.
  3. Add all of those products together.
  4. Divide by the total abundance: Ar=(m1×a1)+(m2×a2)a1+a2A_r = \frac{(m_1 \times a_1) + (m_2 \times a_2)}{a_1 + a_2}Ar​=a1​+a2​(m1​×a1​)+(m2​×a2​)​
  5. The denominator is 100100100 when the abundances are percentages that add to 100100100.
  6. Extend the same pattern for three or more isotopes by adding one product per isotope.
Note
  • Use the total abundance as the denominator even when the percentages do not add to exactly 100100100.
  • Keep one format throughout, so use percentages everywhere or decimals everywhere.

Worked example: weighting three isotopes

  1. An element has isotopes of mass 242424, 252525 and 262626, with abundances of 79%79\%79%, 10%10\%10% and 11%11\%11%.
  2. The abundances add to 100100100, so the denominator is 100100100.
  3. Work out the three products separately before adding, so that a slip in one does not hide inside the total.
Example
  • Find the relative atomic mass of the element.
  • Multiply each isotopic mass by its abundance:
    • 24×79=189624 \times 79 = 189624×79=1896
    • 25×10=25025 \times 10 = 25025×10=250
    • 26×11=28626 \times 11 = 28626×11=286
  • Add the three products:
    • 1896+250+286=24321896 + 250 + 286 = 24321896+250+286=2432
  • Divide by the total abundance:
    • Ar=2432100=24.32A_r = \dfrac{2432}{100} = 24.32Ar​=1002432​=24.32

Checking your answer

  1. Your answer must lie between the lowest and the highest isotopic mass in the data.
  2. It must sit nearer the mass of the most abundant isotope.
  3. Do not round the intermediate products, because rounding early shifts the final value.
  4. Do not take a plain average of the masses, because the isotopes are not equally abundant.
  5. Give ArA_rAr​ with no unit, and to the precision the question asks for.
Self review
  • What is an isotope?
  • How does isotopic abundance affect the value of the relative atomic mass?
  • Why do you divide by 100100100 when the percentage abundances add to 100100100?
  • Why is relative atomic mass written without a unit?
  • An element is 60%60\%60% mass 696969 and 40%40\%40% mass 717171; what is its relative atomic mass?
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Relative atomic mass, ArA_rAr​, is the weighted mean mass of an element's atoms compared with one-twelfth of the mass of a carbon-12 atom. It takes account of both the relative isotopic mass of each isotope and how abundant that isotope is.

An isotope's relative isotopic mass is experimentally determined and is usually close to, but not exactly equal to, its mass number. When a question supplies only mass numbers, these may be used as approximations for the relative isotopic masses. Isotopic abundance is the proportion of atoms that are a particular isotope, given as a percentage, decimal fraction, or count.

Relative atomic mass has no unit because it is a comparison of one mass with another. The answer must lie between the smallest and largest relative isotopic masses used in the calculation.

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An isotope's relative isotopic mass equals its [     ].

2.1.4 Calculating relative atomic mass from isotopic abundance Revision Guide

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Revision notes for Edexcel GCSE Chemistry 2.1.4 Calculating relative atomic mass from isotopic abundance: explanations and worked examples.

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