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10.2.2 Alkenes and the C=C functional group

10.2.2 Alkenes and the C=C functional group

The alkenes and their formulae

Definition

Alkene

An unsaturated hydrocarbon containing a carbon to carbon double bond, with the general formula CnH2n.

  1. Ethene is C2H4\text{C}_2\text{H}_4C2​H4​, the smallest alkene.
  2. Propene is C3H6\text{C}_3\text{H}_6C3​H6​.
  3. Butene is C4H8\text{C}_4\text{H}_8C4​H8​.
  4. Each fits the general formula CnH2n\text{C}_n\text{H}_{2n}Cn​H2n​.
  5. An alkene has two fewer hydrogens than the alkane with the same number of carbons.
Key Idea

The two missing hydrogens are the sign that a double bond is present.

The double bond is the functional group

Definition

Functional group

The group of atoms in a molecule that gives a homologous series its characteristic reactions.

  1. Every alkene contains a carbon to carbon double bond, written C=C\text{C}=\text{C}C=C.
  2. That double bond is the alkene functional group.
  3. Such a group is what gives a family its characteristic reactions.
  4. The rest of the molecule is a chain of carbons carrying hydrogen atoms.
  5. Every alkene reacts in a similar way because every one contains the same group.
Note

The double bond is drawn as two lines between the two carbon atoms.

Drawing the structures

  1. Each carbon still forms four bonds in total, with the double bond counting as two of them.
  2. Ethene is two carbons joined by a double bond, each carrying two hydrogens.
  3. Propene is three carbons, with the double bond between the first and second.
  4. The carbon at the end of the double bond carries two hydrogens, and the middle one carries a single hydrogen.
  5. The third carbon in propene is joined by a single bond and carries three hydrogens.
Example
  • But-1-ene: four carbons with the double bond between the first and second.
  • But-2-ene: four carbons with the double bond between the second and third.
  • Same formula: both are C4H8\text{C}_4\text{H}_8C4​H8​, and only the position of the double bond differs.

Alkenes are unsaturated

Definition

Unsaturated hydrocarbon

A hydrocarbon containing at least one carbon to carbon double bond.

  1. A molecule containing a carbon to carbon double bond is unsaturated.
  2. Unsaturated means the molecule could hold more hydrogen than it does.
  3. The double bond can open so that two more atoms join on.
  4. An alkane cannot do this, since it has no double bond to open.
  5. This difference is what makes alkenes far more reactive than alkanes.
Self review
  • Give the molecular formulae of ethene, propene and butene.
  • What is the functional group in an alkene?
  • Give the general formula of the alkenes.
  • How do but-1-ene and but-2-ene differ?
  • Why are alkenes described as unsaturated?
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An alkene is an unsaturated hydrocarbon containing a carbon to carbon double bond. The general formula of the alkene homologous series is CnH2n\text{C}_n\text{H}_{2n}Cn​H2n​.

Ethene, C2H4\text{C}_2\text{H}_4C2​H4​, is the smallest alkene. Propene is C3H6\text{C}_3\text{H}_6C3​H6​ and butene is C4H8\text{C}_4\text{H}_8C4​H8​.

Compared with an alkane containing the same number of carbon atoms, an alkene has two fewer hydrogen atoms. These two missing hydrogens indicate the presence of a carbon to carbon double bond.

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What is the smallest alkene?

10.2.2 Alkenes and the C=C functional group Revision Guide

  1. GCSE
  2. /Chemistry
  3. /10.2.2 Alkenes and the C=C functional group

Revision notes for Edexcel GCSE Chemistry 10.2.2 Alkenes and the C=C functional group: explanations and worked examples.

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