The alkenes and their formulae
Alkene
An unsaturated hydrocarbon containing a carbon to carbon double bond, with the general formula CnH2n.
- Ethene is C2H4\text{C}_2\text{H}_4C2H4, the smallest alkene.
- Propene is C3H6\text{C}_3\text{H}_6C3H6.
- Butene is C4H8\text{C}_4\text{H}_8C4H8.
- Each fits the general formula CnH2n\text{C}_n\text{H}_{2n}CnH2n.
- An alkene has two fewer hydrogens than the alkane with the same number of carbons.
The two missing hydrogens are the sign that a double bond is present.
The double bond is the functional group
Functional group
The group of atoms in a molecule that gives a homologous series its characteristic reactions.
- Every alkene contains a carbon to carbon double bond, written C=C\text{C}=\text{C}C=C.
- That double bond is the alkene functional group.
- Such a group is what gives a family its characteristic reactions.
- The rest of the molecule is a chain of carbons carrying hydrogen atoms.
- Every alkene reacts in a similar way because every one contains the same group.
The double bond is drawn as two lines between the two carbon atoms.
Drawing the structures
- Each carbon still forms four bonds in total, with the double bond counting as two of them.
- Ethene is two carbons joined by a double bond, each carrying two hydrogens.
- Propene is three carbons, with the double bond between the first and second.
- The carbon at the end of the double bond carries two hydrogens, and the middle one carries a single hydrogen.
- The third carbon in propene is joined by a single bond and carries three hydrogens.
- But-1-ene: four carbons with the double bond between the first and second.
- But-2-ene: four carbons with the double bond between the second and third.
- Same formula: both are C4H8\text{C}_4\text{H}_8C4H8, and only the position of the double bond differs.
Alkenes are unsaturated
Unsaturated hydrocarbon
A hydrocarbon containing at least one carbon to carbon double bond.
- A molecule containing a carbon to carbon double bond is unsaturated.
- Unsaturated means the molecule could hold more hydrogen than it does.
- The double bond can open so that two more atoms join on.
- An alkane cannot do this, since it has no double bond to open.
- This difference is what makes alkenes far more reactive than alkanes.
- Give the molecular formulae of ethene, propene and butene.
- What is the functional group in an alkene?
- Give the general formula of the alkenes.
- How do but-1-ene and but-2-ene differ?
- Why are alkenes described as unsaturated?