Identification of ions by chemical and spectroscopic means (chemistry only)

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Question 20
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This question is about chemical analysis of inorganic salts.

A student investigated sodium sulfate solution and calcium chloride solution using a series of qualitative tests, including flame tests.

This is the method used for the flame tests:

  1. Dip a clean metal wire into sodium sulfate solution.
  2. Place the metal wire into the blue flame of a Bunsen burner.
  3. Observe and record the flame colour produced.
  4. Repeat steps 1 to 3 using the same metal wire with calcium chloride solution, without any cleaning steps in between.
a.

Identify the characteristic flame colour produced by the sodium sulfate solution.

[1]
b.

Calcium compounds normally produce a distinct orange-red flame colour. Explain why the student's method failed to produce a distinct orange-red flame colour when testing the calcium chloride solution.

[2]
c.

In a separate set of tests, the student added sodium hydroxide solution dropwise until in excess to:

  • sodium sulfate solution
  • calcium chloride solution

Describe the observations for each of these two tests.

[2]
d.

To test for the presence of sulfate ions, the student first acidified the sodium sulfate solution with dilute hydrochloric acid. State the name of the reagent that should be added next to confirm the presence of sulfate ions.

[1]
e.

To test for the presence of chloride ions, the student acidified the calcium chloride solution with dilute nitric acid. Name the reagent added to show the presence of chloride ions, and state the observation that confirms their presence.

[2]

Identification of ions by chemical and spectroscopic means (chemistry only) Questions

  1. GCSE
  2. /Chemistry
  3. /Identification of ions by chemical and spectroscopic means (chemistry only)