Skip to content

Course home

7.1.2 Fractional distillation and petrochemicals

7.1.2 Fractional distillation and petrochemicals

Fractional distillation separates crude oil into fractions of similar hydrocarbons

Definition

Hydrocarbon

A compound containing hydrogen and carbon atoms only.

  1. Crude oil is a mixture of many different hydrocarbons.
  2. Fractional distillation is a physical process that separates these hydrocarbons into groups called fractions.
  3. A fraction is a mixture of hydrocarbons whose molecules contain a similar number of carbon atoms.
  4. The separation is possible because hydrocarbons of different sizes have different boiling points.
Key Idea
  • The hydrocarbons are separated using their different boiling points, so they evaporate and condense at different temperatures.
  • The process makes no new substances, because it physically separates a mixture that is already there.

A hot-to-cool column makes hydrocarbons condense at different heights

Definition

Boiling point

The temperature at which a substance rapidly turns from a liquid into a gas throughout the liquid.

  1. Crude oil is heated so that most of it evaporates into a gas.
  2. The hot vapours enter the bottom of a tall fractionating column.
  3. The column has a temperature gradient: it is hot at the bottom and cooler towards the top.
  4. As the vapours rise through the column, they cool down.
  5. Each hydrocarbon condenses back to a liquid once the temperature drops below its boiling point.
  6. Hydrocarbons with high boiling points, which have long chains, condense low down where it is hot.
  7. Hydrocarbons with low boiling points, which have short chains, rise higher and condense near the cooler top.
  8. Each fraction is drawn off the column at the height where it condenses.
Exam technique
  • To explain fractional distillation for full marks, link each step to a change of state: heating causes evaporation, and cooling in the column causes condensation at each hydrocarbon's boiling point.
  • Say the column separates a mixture rather than burning it, and that each fraction is still a mixture, not a pure substance.

Crude-oil fractions become fuels and chemical feedstock

Definition

Liquefied petroleum gases

Hydrocarbon fuels obtained from crude oil that are stored as liquids under pressure and released as gases.

  1. Fuels from crude oil
    1. A fuel is a substance that releases energy when it burns.
    2. Fractions are processed into fuels such as petrol, diesel oil, kerosene, heavy fuel oil and liquefied petroleum gases (LPG).
    3. You are not expected to name any other specific fractions or fuels.
  2. Feedstock for the petrochemical industry
    1. A feedstock is a raw material used to make other useful substances.
    2. The petrochemical industry processes substances from crude oil into fuels and other carbon-based materials.
  3. Useful materials made from petrochemicals
    1. Solvents dissolve other substances.
    2. Lubricants reduce friction between moving surfaces.
    3. Polymers are used to make plastics and synthetic fibres.
    4. Detergents help water lift away grease and dirt.
Common Mistake
  • Do not say the crude oil burns in the column; heating makes the hydrocarbons evaporate, not burn.
  • Do not call a fraction a pure substance; each fraction is still a mixture of hydrocarbons.

Carbon forms huge families of natural and synthetic compounds

Definition

Polymer

A substance made from very large molecules in which many atoms are linked by strong covalent bonds.

  1. Carbon atoms can bond to each other and to hydrogen in many different arrangements.
  2. This lets related carbon compounds be grouped into families that are built in similar ways.
  3. Natural carbon compounds occur in nature, such as the hydrocarbons in crude oil.
  4. Synthetic carbon compounds are made by chemical processes, such as many polymers and detergents.
  5. Carbon's ability to form families of similar compounds is why there is such a vast array of natural and synthetic carbon compounds.
Self review
  • What two changes of state happen during fractional distillation?
  • Why do long-chain hydrocarbons condense low down in the column?
  • What is a feedstock?
  • Name three fuels and two other useful materials made from crude oil.
  • Why can carbon form such a large number of different compounds?
PreviousNext

How was this guide?

Teach Genie

Review 7.1.2 Fractional distillation and petrochemicals by teaching Genie

Teach it back in your own words, spot gaps, and remember it better.

Start teaching
Genie and Baby Genie

Lesson

Recap your knowledge with an interactive lesson

8 minute activity

Start lesson

Labelled fractionating column showing hot bottom, cool top, vapour rising, and fractions condensing at different heights

Crude oil is a mixture of many different hydrocarbons. A hydrocarbon is a compound containing hydrogen and carbon atoms only.

Fractional distillation is a physical process that separates crude oil into fractions. Each fraction is a mixture of hydrocarbons with a similar number of carbon atoms, not a pure substance.

The hydrocarbons are separated because they have different boiling points. No new substances are made during the process.

Flashcards

Remember key concepts with flashcards

25 flashcards

Practice flashcards

What atoms are present in a hydrocarbon?

7.1.2 Fractional distillation and petrochemicals Revision Guide

  1. GCSE
  2. /Chemistry
  3. /7.1.2 Fractional distillation and petrochemicals

Revision notes for AQA GCSE Chemistry 7.1.2 Fractional distillation and petrochemicals: explanations and worked examples.

Revision guides