Exothermic and endothermic reactions

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Question 3
Hard

This question is about the reaction between methane (CH4\text{CH}_4CH4​) and oxygen (O2\text{O}_2O2​).

The equation for the reaction is: CH4(g)+2O2(g)→CO2(g)+2H2O(g)\text{CH}_4(\text{g}) + 2\text{O}_2(\text{g}) \rightarrow \text{CO}_2(\text{g}) + 2\text{H}_2\text{O}(\text{g})CH4​(g)+2O2​(g)→CO2​(g)+2H2​O(g)

a.

What does H2O(g)\text{H}_2\text{O}(\text{g})H2​O(g) represent?

[1]
b.

Calculate the volume of oxygen required to react with 45 cm345\text{ cm}^345 cm3 of methane.

[2]
c.

The reaction is exothermic.

Complete the reaction profile shown below:

Reaction profile template

You should:

  • complete the profile line
  • label the activation energy (EaE_aEa​)
  • label the overall energy change (ΔH\Delta HΔH).
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d.

The displayed formula equation for the reaction of methane with oxygen is: H−∣HH∣-H + 2 O=O → O=C=O + 2 H−O−H\text{H}-\underset{\overset{|}{\text{H}}}{\overset{\text{H}}{|}}\text{-H} \ + \ 2\ \text{O}=\text{O} \ \rightarrow \ \text{O}=\text{C}=\text{O} \ + \ 2\ \text{H}-\text{O}-\text{H}H−H∣∣H​​-H + 2 O=O → O=C=O + 2 H−O−H

The table below shows some of the bond energies:

BondC−H\text{C}-\text{H}C−HO=O\text{O}=\text{O}O=OC=O\text{C}=\text{O}C=OO−H\text{O}-\text{H}O−H
Bond Energy (kJ/mol)XXX495495495799799799463463463

In the reaction, the energy released forming new bonds is 812 kJ/mol812\text{ kJ/mol}812 kJ/mol greater than the energy needed to break existing bonds.

Calculate the bond energy XXX for the C−H\text{C}-\text{H}C−H bond.

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Exothermic and endothermic reactions Questions

  1. GCSE
  2. /Chemistry
  3. /Exothermic and endothermic reactions