This question is about methanol (CH3OH\text{CH}_3\text{OH}CH3OH).
Explain why methanol has a relatively low boiling point compared to giant covalent substances, such as silicon dioxide.
The combustion of methanol in oxygen is an exothermic reaction. Which statement correctly describes the reaction profile for this exothermic reaction?
The balanced chemical equation for the combustion of methanol is:
2CH3OH+3O2→2CO2+4H2O 2\text{CH}_3\text{OH} + 3\text{O}_2 \rightarrow 2\text{CO}_2 + 4\text{H}_2\text{O} 2CH3OH+3O2→2CO2+4H2OThe molecules have the following structural bonds:
The overall energy change for this reaction is −1286 kJ-1286\text{ kJ}−1286 kJ (meaning 1286 kJ1286\text{ kJ}1286 kJ of energy is released).
The table below shows the bond energies for some of these bonds:
| Bond | Bond Energy (kJ/mol\text{kJ/mol}kJ/mol) |
|---|---|
| C−O\text{C}-\text{O}C−O | XXX |
| C−H\text{C}-\text{H}C−H | 413413413 |
| O−H\text{O}-\text{H}O−H | 463463463 |
| O=O\text{O}=\text{O}O=O | 498498498 |
| C=O\text{C}=\text{O}C=O | 805805805 |
Calculate the bond energy of the C−O\text{C}-\text{O}C−O bond (XXX).
13 exam-style questions on AQA GCSE Chemistry 5.1 Exothermic and endothermic reactions, covering 5.1.1 Energy transfer during exothermic and endothermic reactions, 5.1.2 Reaction profiles, and 5.1.3 The energy change of reactions (HT only). Each one has a worked solution and a mark scheme showing where the marks go.