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2.1.1 Chemical bonds

Chemical bonds: strong electrostatic forces that hold particles together

Definition

Delocalised electron

A delocalised electron is an electron that is not tied to one atom or bond and can move through part or all of a structure.

  1. A chemical bond is a strong electrostatic force of attraction that holds particles together in a substance.
  2. An electrostatic force is simply the attraction between opposite electrical charges, one positive and one negative.
  3. When atoms bond, only their outer-shell electrons are rearranged.
    1. These electrons can be transferred, shared in pairs, or shared as delocalised electrons.
  4. There are three types of strong chemical bond: ionic, covalent and metallic.
    1. Each type creates regions of positive and negative charge that attract one another.
Key Idea
  • All three types of bonding rely on attraction between positive and negative charges.
  • Which type forms depends on the elements involved and how their electrons end up arranged.

Choosing the bond type: the elements present tell you how the electrons behave

Definition

Ion

An atom or group of atoms with an overall electrical charge because electrons have been lost or gained.

  1. Ionic bonding forms when a metal combines with a non-metal.
    1. Electrons are transferred from the metal atoms to the non-metal atoms.
    2. The metal atoms become positive ions and the non-metal atoms become negative ions, such as Na+\text{Na}^+Na+ and Cl−\text{Cl}^-Cl−.
    3. Strong electrostatic forces between the oppositely charged ions are the ionic bonds.
  2. Covalent bonding forms in most non-metallic elements and in compounds made only from non-metals.
    1. The non-metal atoms share one or more pairs of electrons.
    2. Each shared pair of negative electrons is attracted to the positive nuclei of both bonded atoms, which is what holds them together.
  3. Metallic bonding occurs in metallic elements and in alloys.
    1. Each metal atom releases its outer electrons into a shared sea of delocalised electrons that are free to move.
    2. Strong electrostatic attraction between the positive metal ions and the negative delocalised electrons holds the structure together.
Example
  • Sodium chloride, NaCl\text{NaCl}NaCl, is ionic because sodium is a metal and chlorine is a non-metal.
  • Oxygen, O2\text{O}_2O2​, is covalent because two non-metal atoms share a pair of electrons.
  • Copper, Cu\text{Cu}Cu, and the alloy brass are metallic because their structures are metal ions sitting in a sea of delocalised electrons.

Explaining a bond: always name the positive part and the negative part

Definition

Alloy

A mixture of two or more elements in which at least one element is a metal.

  1. For ionic bonding, say that positive ions and negative ions attract because opposite charges attract.
    1. Add that electrons are transferred from the metal atoms to the non-metal atoms.
  2. For covalent bonding, say that a negative shared pair of electrons is attracted to the positive nuclei of both atoms.
    1. Add that the atoms share one or more pairs of electrons.
  3. For metallic bonding, say that positive metal ions are attracted to negative delocalised electrons.
    1. Add that the delocalised electrons are shared throughout the whole metal or alloy.
Common Mistake
  • Do not say covalent bonding transfers electrons, because covalently bonded atoms share pairs of electrons.
  • Do not call an ionic bond an attraction between a metal atom and a non-metal atom, because it is between oppositely charged ions.
  • Do not call metallic bonding an attraction between neutral atoms, because it is between positive metal ions and delocalised electrons.

Classifying a substance: identify the elements, then explain the electrons

  1. First decide whether each element present is a metal or a non-metal.
  2. A metal combined with a non-metal usually gives ionic bonding.
  3. Non-metals bonded to non-metals usually give covalent bonding.
  4. A metallic element or an alloy has metallic bonding.
  5. In every explanation, name what happens to the electrons and identify the opposite charges that attract.
Self review
  • What are the three types of strong chemical bond?
  • Which bond type forms between a metal and a non-metal, and what happens to the electrons?
  • In covalent bonding, what is attracted to what?
  • Why are ionic, covalent and metallic bonds all described as electrostatic?
  • In which substances is metallic bonding found?
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Diagram comparing ionic, covalent, and metallic bonding

A chemical bond is a strong electrostatic force of attraction that holds particles together in a substance.

Electrostatic attraction means attraction between opposite electrical charges, such as positive and negative charges. When atoms bond, only their outer-shell electrons are rearranged.

These electrons may be transferred, shared in pairs, or shared as delocalised electrons. The three types of strong chemical bond are ionic, covalent, and metallic.

All three types of bond depend on attraction between positive and negative charges.

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What are the three types of strong chemical bond?

2.1.1 Chemical bonds Revision Guide

  1. GCSE
  2. /Chemistry
  3. /2.1.1 Chemical bonds

Revision notes for AQA GCSE Chemistry 2.1.1 Chemical bonds. Open the guide for explanations and worked examples. Written against the AQA GCSE Chemistry (8462) specification, so the content matches what's examinable rather than general Chemistry background.

Revision guides