Chemical bonds: strong electrostatic forces that hold particles together
Delocalised electron
A delocalised electron is an electron that is not tied to one atom or bond and can move through part or all of a structure.
- A chemical bond is a strong electrostatic force of attraction that holds particles together in a substance.
- An electrostatic force is simply the attraction between opposite electrical charges, one positive and one negative.
- When atoms bond, only their outer-shell electrons are rearranged.
- These electrons can be transferred, shared in pairs, or shared as delocalised electrons.
- There are three types of strong chemical bond: ionic, covalent and metallic.
- Each type creates regions of positive and negative charge that attract one another.
- All three types of bonding rely on attraction between positive and negative charges.
- Which type forms depends on the elements involved and how their electrons end up arranged.
Choosing the bond type: the elements present tell you how the electrons behave
Ion
An atom or group of atoms with an overall electrical charge because electrons have been lost or gained.
- Ionic bonding forms when a metal combines with a non-metal.
- Electrons are transferred from the metal atoms to the non-metal atoms.
- The metal atoms become positive ions and the non-metal atoms become negative ions, such as Na+\text{Na}^+Na+ and Cl−\text{Cl}^-Cl−.
- Strong electrostatic forces between the oppositely charged ions are the ionic bonds.
- Covalent bonding forms in most non-metallic elements and in compounds made only from non-metals.
- The non-metal atoms share one or more pairs of electrons.
- Each shared pair of negative electrons is attracted to the positive nuclei of both bonded atoms, which is what holds them together.
- Metallic bonding occurs in metallic elements and in alloys.
- Each metal atom releases its outer electrons into a shared sea of delocalised electrons that are free to move.
- Strong electrostatic attraction between the positive metal ions and the negative delocalised electrons holds the structure together.
- Sodium chloride, NaCl\text{NaCl}NaCl, is ionic because sodium is a metal and chlorine is a non-metal.
- Oxygen, O2\text{O}_2O2, is covalent because two non-metal atoms share a pair of electrons.
- Copper, Cu\text{Cu}Cu, and the alloy brass are metallic because their structures are metal ions sitting in a sea of delocalised electrons.
Explaining a bond: always name the positive part and the negative part
Alloy
A mixture of two or more elements in which at least one element is a metal.
- For ionic bonding, say that positive ions and negative ions attract because opposite charges attract.
- Add that electrons are transferred from the metal atoms to the non-metal atoms.
- For covalent bonding, say that a negative shared pair of electrons is attracted to the positive nuclei of both atoms.
- Add that the atoms share one or more pairs of electrons.
- For metallic bonding, say that positive metal ions are attracted to negative delocalised electrons.
- Add that the delocalised electrons are shared throughout the whole metal or alloy.
- Do not say covalent bonding transfers electrons, because covalently bonded atoms share pairs of electrons.
- Do not call an ionic bond an attraction between a metal atom and a non-metal atom, because it is between oppositely charged ions.
- Do not call metallic bonding an attraction between neutral atoms, because it is between positive metal ions and delocalised electrons.
Classifying a substance: identify the elements, then explain the electrons
- First decide whether each element present is a metal or a non-metal.
- A metal combined with a non-metal usually gives ionic bonding.
- Non-metals bonded to non-metals usually give covalent bonding.
- A metallic element or an alloy has metallic bonding.
- In every explanation, name what happens to the electrons and identify the opposite charges that attract.
- What are the three types of strong chemical bond?
- Which bond type forms between a metal and a non-metal, and what happens to the electrons?
- In covalent bonding, what is attracted to what?
- Why are ionic, covalent and metallic bonds all described as electrostatic?
- In which substances is metallic bonding found?
