Carboxylic acids are weak because they only partially ionise
Carboxylic acid
An organic compound containing the functional group -COOH\text{-COOH}-COOH.
- A weak acid ionises only partially in water, so only a small proportion of its molecules form ions.
- Carboxylic acids are weak acids, because most of their molecules stay un-ionised in solution.
- Ethanoic acid is a typical carboxylic acid, and its partial ionisation is shown here.
- CH3COOH(aq)⇌H+(aq)+CH3COO−(aq)\text{CH}_3\text{COOH}(aq) \rightleftharpoons \text{H}^{+}(aq) + \text{CH}_3\text{COO}^{-}(aq)CH3COOH(aq)⇌H+(aq)+CH3COO−(aq)
- The reversible arrow shows molecules forming ions and ions reforming molecules.
- At any moment most of the acid is present as molecules, with only a small proportion as ions.
Partial ionisation gives fewer hydrogen ions and a higher pH
pH
A measure of the hydrogen ion concentration in an aqueous solution.
- The pH of a solution depends on its concentration of H+(aq)\text{H}^{+}(aq)H+(aq) ions.
- A higher H+(aq)\text{H}^{+}(aq)H+(aq) concentration gives a lower pH.
- A weak carboxylic acid makes fewer H+(aq)\text{H}^{+}(aq)H+(aq) ions than a strong acid of the same concentration, because it only partially ionises.
- So a carboxylic acid has a higher pH than a strong acid of the same concentration, though still below 7.
- Compare 0.10 mol/dm30.10\ \text{mol/dm}^30.10 mol/dm3 hydrochloric acid and ethanoic acid.
- Hydrochloric acid ionises completely and ethanoic acid only partially, so the hydrochloric acid has the higher hydrogen ion concentration and the lower pH.
Strength describes ionisation, not concentration
Ionisation
The process in which neutral particles form ions, such as an acid molecule forming H+\text{H}^{+}H+ and a negative ion in water.
- Acid strength is the proportion of acid molecules that ionise in water.
- Concentration is how much acid is dissolved in a given volume of solution.
- A concentrated carboxylic acid is still weak, because only a proportion of its molecules ionise.
- A dilute strong acid is still strong, because the molecules present ionise completely.
- A weak carboxylic acid is not neutral, because partial ionisation still makes some H+(aq)\text{H}^{+}(aq)H+(aq) ions.
- Do not say a carboxylic acid is weak because it is dilute; weak means partially ionised, while dilute means low concentration.
- Keep the two ideas separate: strength is about ionisation and concentration is about how much is dissolved.
Putting the explanation together
- Start by saying carboxylic acids partially ionise in water.
- Explain that partial ionisation makes fewer H+(aq)\text{H}^{+}(aq)H+(aq) ions than complete ionisation at the same concentration.
- Link the lower hydrogen ion concentration to the higher pH.
- Do not say a weak acid does not ionise, because some molecules do form ions.
- Why are carboxylic acids weak acids?
- How does partial ionisation affect pH compared with a strong acid of the same concentration?
- Does “weak” mean the same as “dilute”?
- What does the reversible arrow in the ionisation equation show?