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Periodicity

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Question 1
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The graph below shows the variation in first ionisation energy across Period 3:

First ionisation energy across Period 3

Which statement best explains why magnesium (Mg\text{Mg}Mg) has a larger first ionisation energy than aluminium (Al\text{Al}Al)?

Mg\text{Mg}Mg has a smaller atomic radius than Al\text{Al}Al, resulting in a stronger electrostatic attraction to its outer electrons.

The outer electron in Al\text{Al}Al is lost from a 3p\text{3p}3p subshell, which is higher in energy and better shielded than the outer electron of Mg\text{Mg}Mg in the 3s\text{3s}3s subshell.

Mg\text{Mg}Mg has a larger nuclear charge than Al\text{Al}Al, which binds its outer electrons more tightly.

There is greater spin-pair repulsion in the outer subshell of Mg\text{Mg}Mg than in that of Al\text{Al}Al.

Periodicity Questions

  1. A Level
  2. /Chemistry
  3. /Periodicity