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Atoms and reactions

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Question 58

This question is about transition metals, oxides of iron, and differences in lattice structures of oxides.

Iron forms several oxides including FeO\text{FeO}FeO, Fe2O3\text{Fe}_2\text{O}_3Fe2​O3​, and Fe3O4\text{Fe}_3\text{O}_4Fe3​O4​.

A student carries out an experiment to identify an unknown iron oxide by reducing it to iron metal. The student heats the unknown iron oxide in a horizontal tube in a stream of hydrogen gas, H2\text{H}_2H2​.

Student's method:

  • Weigh an empty dish.
  • Add the iron oxide to the dish and reweigh.
  • Set up the apparatus and pass hydrogen gas through the tube.
  • Heat the dish for 10 minutes.
  • Pass cold air through the tube to cool the dish and contents.
  • Weigh the dish and contents.
a.

Write the balanced equation for the reduction of Fe3O4\text{Fe}_3\text{O}_4Fe3​O4​ with H2\text{H}_2H2​ to form iron and steam.

[1]
b.

The student wears safety glasses and a lab coat. State, with a reason, one other important safety precaution the student should take when carrying out this experiment involving hydrogen.

[2]
c.

Suggest two modifications that the student could make to their method to be confident that all the oxygen had been removed from the iron oxide. Explain your reasoning.

[4]
d.

After making suitable modifications, the student repeats the experiment to obtain the following accurate results:

  • Mass of empty dish = 12.240 g12.240\text{ g}12.240 g
  • Mass of dish + iron oxide = 16.230 g16.230\text{ g}16.230 g
  • Mass of dish + iron at the end of the experiment = 15.030 g15.030\text{ g}15.030 g

Calculate the empirical formula of the iron oxide.

[3]
e.

SiO2\text{SiO}_2SiO2​ and SO2\text{SO}_2SO2​ are acidic oxides. Solid SiO2\text{SiO}_2SiO2​ melts at 1713 ∘C1713\text{ }^\circ\text{C}1713 ∘C while solid SO2\text{SO}_2SO2​ melts at −72 ∘C-72\text{ }^\circ\text{C}−72 ∘C.

Suggest the type of lattice structure in solid SiO2\text{SiO}_2SiO2​ and in solid SO2\text{SO}_2SO2​, and explain the difference in melting points in terms of the types of force within each lattice structure.

[5]

Atoms and reactions Questions

  1. A Level
  2. /Chemistry
  3. /Atoms and reactions