Acids, bases and buffers

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Question 19
Medium

Chlorocresol is an antiseptic and preservative with the structure shown below.

The chemical structure of chlorocresol. It consists of a benzene ring with a hydroxyl group (-OH) at position 1 (top position), a methyl group (-CH3) at position 3, and a chlorine atom (-Cl) at position 4 (bottom position).

a.

Chlorocresol is a weak Brønsted–Lowry acid.

What is the systematic name of chlorocresol?

[1]
b.

Predict the number of peaks in a 13C^{13}\text{C}13C NMR spectrum of chlorocresol.

[1]
c.

A student measures the pH of an antiseptic solution containing chlorocresol to be 5.35.

The label on the bottle shows the percentage of chlorocresol in the solution as 2.85% (weight/volume), meaning 100 cm3100\text{ cm}^3100 cm3 of the solution contains 2.85 g2.85\text{ g}2.85 g of chlorocresol.

Assume the following:

  • Chlorocresol is the only acidic component in the solution.
  • Chlorocresol is a weak monobasic acid.
  • The density of the solution is 1.00 g cm−31.00\text{ g cm}^{-3}1.00 g cm−3.

Write the equation, using molecular formulae, for the acid dissociation of chlorocresol, and calculate the acid dissociation constant, KaK_{\text{a}}Ka​, for chlorocresol.

[5]

Acids, bases and buffers Questions

  1. A Level
  2. /Chemistry
  3. /Acids, bases and buffers