Transition metals (A-level only)

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Question 4
Medium
1.

Explain how nitrogen monoxide (NO\text{NO}NO) is formed in industrial gas turbine combustors.

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2.

State one environmental or health hazard associated with the emission of oxides of nitrogen.

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3.

To mitigate emissions, industrial power plants utilize selective catalytic reduction (SCR) systems where ammonia, NH3\text{NH}_3NH3​, reacts with nitrogen dioxide, NO2\text{NO}_2NO2​, in the presence of a catalyst to form nitrogen and water.

  • Give the oxidation state of nitrogen in each of NO2\text{NO}_2NO2​, NH3\text{NH}_3NH3​, and N2\text{N}_2N2​.
  • Complete and balance the equation for this reaction: ‾ NO2+‾ NH3→‾ N2+‾ H2O\underline{\quad}\ \text{NO}_2 + \underline{\quad}\ \text{NH}_3 \rightarrow \underline{\quad}\ \text{N}_2 + \underline{\quad}\ \text{H}_2\text{O}​ NO2​+​ NH3​→​ N2​+​ H2​O
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4.

The SCR system uses a solid metal oxide catalyst, such as vanadium(V) oxide, to facilitate this process. State the meaning of the term heterogeneous catalyst.

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5.

Carbon monoxide (CO\text{CO}CO) is another pollutant that can be released from gas turbines if the fuel-to-air ratio is incorrect. Explain why carbon monoxide is formed instead of carbon dioxide.

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Transition metals (A-level only) Questions

  1. A Level
  2. /Chemistry
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