Transition metals (A-level only)

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Question 13
Medium

Solution X contains the compound [Cu(H2O)6]SO4[\text{Cu}(\text{H}_2\text{O})_6]\text{SO}_4[Cu(H2​O)6​]SO4​.

a.

State the type of bonding between the oxygen and hydrogen atoms in the water ligands of this compound.

[1]
b.

State why the sulfate ions in this compound are not considered to be ligands.

[1]
c.

Concentrated hydrochloric acid (reagent Y) was added to a sample of solution X to form a yellow-green solution Z. Identify reagent Y and write an ionic equation for the reaction that occurs when solution X is turned into solution Z.

[3]
d.

Aqueous sodium carbonate was added to another sample of solution X to form a blue-green precipitate W. Identify the blue-green solid W.

[1]
e.

Explain why colorimetry cannot be used to determine the concentration of solutions containing [Sc(H2O)6]3+[\text{Sc}(\text{H}_2\text{O})_6]^{3+}[Sc(H2​O)6​]3+. In your answer, refer to the electron configuration of the metal ion.

[3]

Transition metals (A-level only) Questions

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