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Oxidation, reduction and redox equations

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12
Question 1

The percentage by mass of iron in a steel wire is determined by a student.

The student:

  • reacts 800 mg800\text{ mg}800 mg of the wire with an excess of sulfuric acid, so that all of the iron in the wire forms Fe2+(aq)\text{Fe}^{2+}(\text{aq})Fe2+(aq)
  • makes up the volume of the Fe2+(aq)\text{Fe}^{2+}(\text{aq})Fe2+(aq) solution to exactly 100 cm3100\text{ cm}^3100 cm3
  • takes 25.0 cm325.0\text{ cm}^325.0 cm3 portions of the Fe2+(aq)\text{Fe}^{2+}(\text{aq})Fe2+(aq) solution
  • titrates each portion with 0.0200 mol dm−30.0200\text{ mol dm}^{-3}0.0200 mol dm−3 potassium manganate(VII) solution.
1.

Give the equation for the reaction between iron and sulfuric acid.

[1]
2.

The titration results are shown in Table 1.

123
Final volume / cm3\text{cm}^3cm323.9046.8022.80
Initial volume / cm3\text{cm}^3cm30.0023.900.00
Titre / cm3\text{cm}^3cm323.9022.9022.80

Calculate the mean titre.

[2]
3.

Give the overall ionic equation for the oxidation of Fe2+\text{Fe}^{2+}Fe2+ by manganate(VII) ions, MnO4−\text{MnO}_4^-MnO4−​, in acidic conditions.

[1]
4.

State the colour change seen at the end point of the titration.

[1]
5.

Name the piece of apparatus used for these stages of the method.

  • Taking the 25.0 cm325.0\text{ cm}^325.0 cm3 portions
  • Adding the potassium manganate(VII) solution
[2]
6.

The balance used to weigh the 800 mg800\text{ mg}800 mg of iron wire has an uncertainty of ±0.005 g\pm 0.005\text{ g}±0.005 g. A container was weighed and its mass was subtracted from the total mass of the container and wire. Calculate the percentage uncertainty in using the balance. Give your answer to two decimal places.

[2]

Oxidation, reduction and redox equations Questions

  1. A Level
  2. /Chemistry
  3. /Oxidation, reduction and redox equations