Organic analysis

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Question 12
Medium

A sample of chloroethane is analysed using a time of flight (TOF) mass spectrometer, where fragment ions are formed by electron impact ionisation.

A 37Cl+^{37}\text{Cl}^+37Cl+ fragment ion with a kinetic energy of 2.150×10−14 J2.150 \times 10^{-14}\text{ J}2.150×10−14 J travels through a flight tube of length 1.450 m1.450\text{ m}1.450 m.

The kinetic energy of the ion is given by the equation:

KE=12mv2KE = \frac{1}{2}mv^2KE=21​mv2

where:

  • mmm = mass of one ion in kg\text{kg}kg
  • vvv = speed of the ion in m s−1\text{m s}^{-1}m s−1
  • KEKEKE = kinetic energy of the ion in J\text{J}J

Calculate the time, in seconds, for this ion to travel the length of the flight tube to reach the detector. Give your answer to 3 significant figures.

The Avogadro constant, L=6.022×1023 mol−1L = 6.022 \times 10^{23}\text{ mol}^{-1}L=6.022×1023 mol−1.

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Organic analysis Questions

  1. A Level
  2. /Chemistry
  3. /Organic analysis