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Synthetic polymers

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Question 4

Butane (C4H10\text{C}_4\text{H}_{10}C4​H10​) is used as a starting material to manufacture addition polymers. It is first cracked to form propene (C3H6\text{C}_3\text{H}_6C3​H6​).

a.

Identify the gas that also forms in this reaction.

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b.

Butane is described as saturated. What feature of a butane molecule is responsible for this description?

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c.

Bromine can undergo an addition reaction with propene. (i) Complete the equation to show the displayed formula of the product of the reaction between propene and bromine.

HH∣∣C=C∣∣HCH3+Br−Br→ \begin{array}{ccc} \text{H} & & \text{H} \\ | & & | \\ \text{C} & = & \text{C} \\ | & & | \\ \text{H} & & \text{CH}_3 \end{array} + \text{Br}-\text{Br} \rightarrow H∣C∣H​=​H∣C∣CH3​​+Br−Br→
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d.

(ii) Which is the correct statement about the test involving bromine water with propene?

  • A the reaction is a substitution reaction
  • B the orange-brown bromine water is decolourised
  • C the reaction produces a white height
  • D propene is an orange-brown gas
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e.

Alkenes can be polymerised. Part of the structure of poly(propene) can be represented as

HCH3HCH3∣∣∣∣−C−C−C−C−∣∣∣∣HHHH \begin{array}{cccc} \text{H} & \text{CH}_3 & \text{H} & \text{CH}_3 \\ | & | & | & | \\ -\text{C} & -\text{C} & -\text{C} & -\text{C}- \\ | & | & | & | \\ \text{H} & \text{H} & \text{H} & \text{H} \end{array} H∣−C∣H​CH3​∣−C∣H​H∣−C∣H​CH3​∣−C−∣H​

This structure shows the atoms coming from two molecules of propene. Draw part of the structure of poly(pent-1-ene) that shows the atoms coming from two molecules of pent-1-ene (CH2=CH−CH2−CH2−CH3\text{CH}_2=\text{CH}-\text{CH}_2-\text{CH}_2-\text{CH}_3CH2​=CH−CH2​−CH2​−CH3​).

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f.

The repeat unit of another addition polymer can be represented as

FF∣∣−C−C−∣∣FF \begin{array}{cc} \text{F} & \text{F} \\ | & | \\ -\text{C} & -\text{C}- \\ | & | \\ \text{F} & \text{F} \end{array} F∣−C∣F​F∣−C−∣F​

Draw the structure of the monomer used to make this polymer.

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g.

The disposal of most addition polymers is a problem because they do not biodegrade. (i) What is meant by the term biodegradable?

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h.

(ii) Identify the property that prevents addition polymers from easily biodegrading.

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Synthetic polymers Questions

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