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3.3.1 Units of concentration

Concentration

Definition

Solute

The substance that dissolves in a solvent to form a solution.

Definition

Solution

A mixture formed when a solute dissolves completely and spreads evenly through a solvent.

Definition

Concentration

The quantity of solute dissolved in each cubic decimetre of solution, measured in g/dm3\text{g/dm}^3g/dm3 or mol/dm3\text{mol/dm}^3mol/dm3.

  1. When a solute dissolves in a solvent such as water, it spreads evenly through the liquid to form a solution.
  2. The concentration of a solution tells you how much solute is present in a fixed volume of that solution.
  3. A concentrated solution has a large amount of solute in a given volume, while a dilute solution has a small amount in the same volume.
  4. In terms of particles, a more concentrated solution has more solute particles in each unit of volume, so they are closer together.
  5. Adding more water to a solution makes it more dilute, because the same amount of solute is spread through a larger volume.
  6. Concentration is always measured per volume of the final solution, not per volume of solvent added.

The cubic decimetre

Definition

Cubic decimetre

A unit of volume, written dm3\text{dm}^3dm3, equal to the volume of a cube with sides 10 cm10\ \text{cm}10 cm long, which is 1000 cm31000\ \text{cm}^31000 cm3.

  1. Chemists measure the volume of a solution in cubic decimetres, written dm3\text{dm}^3dm3, rather than in litres.
  2. A cubic decimetre is the volume of a cube 10 cm10\ \text{cm}10 cm long on every side, so it holds 10×10×10=1000 cm310 \times 10 \times 10 = 1000\ \text{cm}^310×10×10=1000 cm3.
  3. One dm3\text{dm}^3dm3 is the same volume as one litre, which is about the size of a large carton of juice.
  4. Smaller volumes, such as those read from a measuring cylinder or a burette, are measured in cubic centimetres, cm3\text{cm}^3cm3.

Concentration in grams per cubic decimetre

  1. A concentration in g/dm3\text{g/dm}^3g/dm3 gives the mass of solute in grams dissolved in each 1 dm31\ \text{dm}^31 dm3 of solution.
  2. Read the unit as "grams per cubic decimetre", where the solidus, ///, means "per".
  3. A solution labelled 40 g/dm340\ \text{g/dm}^340 g/dm3 contains 40 g40\ \text{g}40 g of solute in every 1 dm31\ \text{dm}^31 dm3 of solution.
  4. This unit is useful when the mass of solute has been measured on a balance.
  5. The same unit is sometimes printed as g dm−3\text{g dm}^{-3}g dm−3, which means exactly the same thing.

Concentration in moles per cubic decimetre

  1. A concentration in mol/dm3\text{mol/dm}^3mol/dm3 gives the amount of solute in moles dissolved in each 1 dm31\ \text{dm}^31 dm3 of solution.
  2. The mole, symbol mol\text{mol}mol, is the unit chemists use for an amount of substance, and it counts particles rather than measuring their mass.
  3. Read the unit as "moles per cubic decimetre".
  4. A bottle of dilute hydrochloric acid labelled 1.0 mol/dm31.0\ \text{mol/dm}^31.0 mol/dm3 contains 1.0 mol1.0\ \text{mol}1.0 mol of hydrogen chloride in every 1 dm31\ \text{dm}^31 dm3 of solution.
  5. Most laboratory solutions, such as acids and alkalis, have their concentrations given in mol/dm3\text{mol/dm}^3mol/dm3.
  6. The same unit is sometimes printed as mol dm−3\text{mol dm}^{-3}mol dm−3.

Comparing concentrations

  1. Two concentrations can be compared directly only when they are given in the same unit.
  2. Within one unit, the larger number always means the more concentrated solution.
    1. A 2.0 mol/dm32.0\ \text{mol/dm}^32.0 mol/dm3 solution of sodium hydroxide is twice as concentrated as a 1.0 mol/dm31.0\ \text{mol/dm}^31.0 mol/dm3 solution of sodium hydroxide.
  3. Always write the unit with the number, because 0.50.50.5 on its own could mean 0.5 g/dm30.5\ \text{g/dm}^30.5 g/dm3 or 0.5 mol/dm30.5\ \text{mol/dm}^30.5 mol/dm3, which are very different amounts.
Example

Reading concentration labels

  • A bottle of sulfuric acid in the school laboratory is labelled 0.5 mol/dm30.5\ \text{mol/dm}^30.5 mol/dm3.
  • Every 1 dm31\ \text{dm}^31 dm3 of this acid contains 0.5 mol0.5\ \text{mol}0.5 mol of sulfuric acid.
  • A sugar solution made for a food test is labelled 40 g/dm340\ \text{g/dm}^340 g/dm3.
  • Every 1 dm31\ \text{dm}^31 dm3 of this solution contains 40 g40\ \text{g}40 g of dissolved sugar.
Common Mistake
  • Do not write g/cm3\text{g/cm}^3g/cm3 for a concentration, because that unit is used for density.
  • Do not measure concentration per volume of solvent, because it is always per dm3\text{dm}^3dm3 of the final solution.
  • Do not leave out the unit after a concentration, because the number alone does not show whether mass or moles was used.
Self review
  • What does the concentration of a solution measure?
  • Which two units are used for concentration?
  • How many cm3\text{cm}^3cm3 are there in 1 dm31\ \text{dm}^31 dm3?
  • What does a concentration of 25 g/dm325\ \text{g/dm}^325 g/dm3 mean?
  • What is the difference between a concentrated solution and a dilute solution?
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Revision notes for CIE IGCSE Chemistry 3.3.1 Units of concentration: explanations and worked examples.

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