Concentration
Definition
Solute
The substance that dissolves in a solvent to form a solution.
Definition
Solution
A mixture formed when a solute dissolves completely and spreads evenly through a solvent.
Definition
Concentration
The quantity of solute dissolved in each cubic decimetre of solution, measured in g/dm3\text{g/dm}^3g/dm3 or mol/dm3\text{mol/dm}^3mol/dm3.
- When a solute dissolves in a solvent such as water, it spreads evenly through the liquid to form a solution.
- The concentration of a solution tells you how much solute is present in a fixed volume of that solution.
- A concentrated solution has a large amount of solute in a given volume, while a dilute solution has a small amount in the same volume.
- In terms of particles, a more concentrated solution has more solute particles in each unit of volume, so they are closer together.
- Adding more water to a solution makes it more dilute, because the same amount of solute is spread through a larger volume.
- Concentration is always measured per volume of the final solution, not per volume of solvent added.
The cubic decimetre
Definition
Cubic decimetre
A unit of volume, written dm3\text{dm}^3dm3, equal to the volume of a cube with sides 10 cm10\ \text{cm}10 cm long, which is 1000 cm31000\ \text{cm}^31000 cm3.
- Chemists measure the volume of a solution in cubic decimetres, written dm3\text{dm}^3dm3, rather than in litres.
- A cubic decimetre is the volume of a cube 10 cm10\ \text{cm}10 cm long on every side, so it holds 10×10×10=1000 cm310 \times 10 \times 10 = 1000\ \text{cm}^310×10×10=1000 cm3.
- One dm3\text{dm}^3dm3 is the same volume as one litre, which is about the size of a large carton of juice.
- Smaller volumes, such as those read from a measuring cylinder or a burette, are measured in cubic centimetres, cm3\text{cm}^3cm3.
Concentration in grams per cubic decimetre
- A concentration in g/dm3\text{g/dm}^3g/dm3 gives the mass of solute in grams dissolved in each 1 dm31\ \text{dm}^31 dm3 of solution.
- Read the unit as "grams per cubic decimetre", where the solidus, ///, means "per".
- A solution labelled 40 g/dm340\ \text{g/dm}^340 g/dm3 contains 40 g40\ \text{g}40 g of solute in every 1 dm31\ \text{dm}^31 dm3 of solution.
- This unit is useful when the mass of solute has been measured on a balance.
- The same unit is sometimes printed as g dm−3\text{g dm}^{-3}g dm−3, which means exactly the same thing.
Concentration in moles per cubic decimetre
- A concentration in mol/dm3\text{mol/dm}^3mol/dm3 gives the amount of solute in moles dissolved in each 1 dm31\ \text{dm}^31 dm3 of solution.
- The mole, symbol mol\text{mol}mol, is the unit chemists use for an amount of substance, and it counts particles rather than measuring their mass.
- Read the unit as "moles per cubic decimetre".
- A bottle of dilute hydrochloric acid labelled 1.0 mol/dm31.0\ \text{mol/dm}^31.0 mol/dm3 contains 1.0 mol1.0\ \text{mol}1.0 mol of hydrogen chloride in every 1 dm31\ \text{dm}^31 dm3 of solution.
- Most laboratory solutions, such as acids and alkalis, have their concentrations given in mol/dm3\text{mol/dm}^3mol/dm3.
- The same unit is sometimes printed as mol dm−3\text{mol dm}^{-3}mol dm−3.
Comparing concentrations
- Two concentrations can be compared directly only when they are given in the same unit.
- Within one unit, the larger number always means the more concentrated solution.
- A 2.0 mol/dm32.0\ \text{mol/dm}^32.0 mol/dm3 solution of sodium hydroxide is twice as concentrated as a 1.0 mol/dm31.0\ \text{mol/dm}^31.0 mol/dm3 solution of sodium hydroxide.
- Always write the unit with the number, because 0.50.50.5 on its own could mean 0.5 g/dm30.5\ \text{g/dm}^30.5 g/dm3 or 0.5 mol/dm30.5\ \text{mol/dm}^30.5 mol/dm3, which are very different amounts.
Example
Reading concentration labels
- A bottle of sulfuric acid in the school laboratory is labelled 0.5 mol/dm30.5\ \text{mol/dm}^30.5 mol/dm3.
- Every 1 dm31\ \text{dm}^31 dm3 of this acid contains 0.5 mol0.5\ \text{mol}0.5 mol of sulfuric acid.
- A sugar solution made for a food test is labelled 40 g/dm340\ \text{g/dm}^340 g/dm3.
- Every 1 dm31\ \text{dm}^31 dm3 of this solution contains 40 g40\ \text{g}40 g of dissolved sugar.
Common Mistake
- Do not write g/cm3\text{g/cm}^3g/cm3 for a concentration, because that unit is used for density.
- Do not measure concentration per volume of solvent, because it is always per dm3\text{dm}^3dm3 of the final solution.
- Do not leave out the unit after a concentration, because the number alone does not show whether mass or moles was used.
Self review
- What does the concentration of a solution measure?
- Which two units are used for concentration?
- How many cm3\text{cm}^3cm3 are there in 1 dm31\ \text{dm}^31 dm3?
- What does a concentration of 25 g/dm325\ \text{g/dm}^325 g/dm3 mean?
- What is the difference between a concentrated solution and a dilute solution?