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10.1.2 Substances in natural water and water treatment

Substances in natural water

Definition

Sewage

Waste water from homes, farms and industry that contains human and animal waste and harmful microbes.

  1. Water from natural sources, such as rivers, lakes, reservoirs and underground rocks, is never pure.
  2. As water flows over land and through rocks and soil, it dissolves some substances and carries others along with it.
  3. Water from natural sources may contain the following substances.
    1. Dissolved oxygen, which dissolves into the water from the air and is also released by water plants.
    2. Metal compounds, which dissolve out of the rocks and soil that the water flows through.
    3. Plastics, from litter and waste that are dropped or washed into rivers, lakes and seas.
    4. Sewage, from homes and farms, and from sewers that leak or overflow after heavy rain.
    5. Harmful microbes, such as bacteria, many of which come from sewage.
    6. Nitrates, which are washed off farmland that has been treated with fertilisers.
    7. Phosphates, which come from fertilisers and from the detergents in waste water from homes.
  4. Some of these substances are beneficial to living things, while others are potentially harmful.

Beneficial substances

  1. Dissolved oxygen is needed by aquatic life, because fish and other water animals take in oxygen from the water for respiration.
  2. A river or lake with plenty of dissolved oxygen can support a large number and variety of living things.
  3. Some metal compounds provide essential minerals for life.
  4. For example, dissolved calcium compounds provide the calcium that people need for healthy bones and teeth, and magnesium compounds provide magnesium.
  5. This is why the label on a bottle of mineral water lists the dissolved minerals that the water contains.

Harmful substances

Definition

Deoxygenation

The loss of dissolved oxygen from water, which leaves too little oxygen for fish and other aquatic life.

  1. Some metal compounds are toxic, such as compounds of lead and mercury, which poison people and aquatic life even at low concentrations.
  2. Toxic metal compounds can build up in the bodies of fish over time, so they also harm the animals and people that eat the fish.
  3. Some plastics harm aquatic life, because animals become trapped in plastic waste or swallow small pieces of plastic, which block their digestive systems.
  4. Most plastics do not break down in water, so plastic waste keeps causing harm for many years.
  5. Sewage contains harmful microbes, which cause diseases such as cholera and typhoid if the water is drunk without being treated.
  6. Nitrates and phosphates lead to the deoxygenation of water, so the amount of dissolved oxygen in the water falls.
  7. Without enough dissolved oxygen, fish and other aquatic organisms cannot respire, so they die and the aquatic life of the river or lake is damaged.

Treating the domestic water supply

Definition

Sedimentation

The settling of insoluble solid particles to the bottom of a liquid under gravity when the liquid is left to stand.

Definition

Filtration

The separation of an insoluble solid from a liquid by passing the mixture through a filter that holds back the solid.

Definition

Chlorination

The addition of chlorine to the water supply to kill harmful microbes.

  1. Water taken from rivers and reservoirs must be treated before it is safe to supply to homes as drinking water.
  2. Treatment happens in a set order of stages, and each stage removes or deals with a different type of substance.
  3. Sedimentation is the first stage.
    1. The water is left to stand in large tanks, so that heavy insoluble particles, such as sand, grit and mud, sink to the bottom under gravity.
    2. The cleaner water is then drawn off from the top of the tanks.
  4. Filtration is the second stage.
    1. The water passes slowly through beds of sand and gravel, which trap the smaller insoluble particles that did not settle out.
    2. Sedimentation and filtration together remove solids from the water.
  5. Carbon is used in the third stage.
    1. The water passes through granules or powder of carbon, which removes the dissolved substances that cause unpleasant tastes and odours.
    2. The unwanted substances stick to the very large surface area of the tiny carbon particles, so they are held back while the water passes on.
  6. Chlorination is the final stage.
    1. A small, carefully controlled amount of chlorine is added to the water to kill microbes, such as bacteria, that could cause disease.
    2. A little chlorine stays in the water as it travels through the pipes, so it keeps killing microbes until the water reaches the tap.
  7. Treated tap water is safe to drink, but it is not pure, because dissolved salts pass through every stage of the treatment.
Example

Following river water through a treatment works

  • Water arrives from the river cloudy and brown, carrying sand, mud, leaves, dissolved salts, substances with an earthy smell and bacteria.
  • After sedimentation, the sand and most of the mud have settled at the bottom of the tank, but the water is still slightly cloudy.
  • After filtration through sand and gravel, the remaining small particles have been trapped, so the water is clear.
  • After treatment with carbon, the earthy taste and smell have gone.
  • After chlorination, the bacteria have been killed, so the water is safe to drink.
  • The dissolved salts are still present at the end, which is why tap water is safe to drink but not pure.
Exam technique

Describing water treatment

  • Match each stage to its job: sedimentation and filtration remove solids, carbon removes tastes and odours, and chlorination kills microbes.
  • Use the verb kill for chlorination, because saying that chlorine cleans or purifies the water does not state what it does.
  • When you classify a substance in natural water, give the reason, for example that dissolved oxygen is beneficial because it is needed by aquatic life.
  • For nitrates and phosphates, the effect to give is deoxygenation of the water, leading to damage to aquatic life.
Common Mistake
  • Do not say that filtration removes dissolved substances, because a filter traps only insoluble solids.
  • Do not say that chlorine removes microbes from the water, because it kills them and they stay in the water.
  • Do not say that carbon kills bacteria, because carbon removes tastes and odours.
  • Do not describe all metal compounds in water as harmful, because some provide essential minerals for life.
Self review
  • Name two substances in natural water that are beneficial and give the reason for each.
  • Why is water that contains sewage harmful to drink?
  • What effect do nitrates and phosphates have on the water in a river or lake?
  • Which two stages of water treatment remove solids?
  • What is the purpose of carbon and of chlorination in water treatment?
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10.1.2 Substances in natural water and water treatment Revision Guide

  1. IGCSE
  2. /Chemistry
  3. /10.1.2 Substances in natural water and water treatment

Revision notes for CIE IGCSE Chemistry 10.1.2 Substances in natural water and water treatment: explanations and worked examples.

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