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10.3.3 Greenhouse gases and catalytic converters

How greenhouse gases cause global warming

Definition

Greenhouse gas

A gas in the atmosphere, such as carbon dioxide or methane, that absorbs thermal energy emitted by the Earth's surface and so reduces the loss of thermal energy to space.

Definition

Global warming

The increase in the average temperature of the Earth's surface and atmosphere.

  1. Carbon dioxide and methane are greenhouse gases.
  2. Thermal energy from the Sun travels through the atmosphere and reaches the Earth.
  3. Some of this energy is reflected straight back into space by clouds, ice and the Earth's surface.
  4. The rest is absorbed by the Earth's surface, which warms up.
  5. The warm surface then emits thermal energy back out towards space as infrared radiation.
  6. Greenhouse gases in the atmosphere absorb some of this thermal energy.
  7. The greenhouse gas molecules then emit the thermal energy again in all directions, so some of it travels back towards the Earth's surface.
  8. This reduces thermal energy loss to space, so the Earth's surface and the lower atmosphere stay warmer than they otherwise would.
  9. A small amount of this warming is natural, and without it the Earth would be too cold for most life.
  10. Higher levels of carbon dioxide and methane absorb and re-emit more of the thermal energy, so even less is lost to space.
  11. The average temperature of the Earth therefore rises, which is increased global warming.

Oxides of nitrogen in car engines

  1. The air drawn into a car engine is about 78%78\%78% nitrogen and 21%21\%21% oxygen.
  2. Nitrogen is normally very unreactive, because a strong triple bond holds the two atoms together in each N2\mathrm{N_{2}}N2​ molecule.
  3. Inside the engine, the burning fuel produces a very high temperature.
  4. At this high temperature there is enough energy for nitrogen and oxygen from the air to react together, forming nitrogen monoxide: N2+O2→2NO\mathrm{N_{2} + O_{2} \rightarrow 2NO}N2​+O2​→2NO.
  5. Nitrogen monoxide then reacts with more oxygen to form nitrogen dioxide: 2NO+O2→2NO2\mathrm{2NO + O_{2} \rightarrow 2NO_{2}}2NO+O2​→2NO2​.
  6. The nitrogen in these oxides comes from the air, not from the fuel, because petrol is a mixture of hydrocarbons and contains no nitrogen.

Removing oxides of nitrogen with catalytic converters

Definition

Catalytic converter

A device in the exhaust system of a vehicle that uses a catalyst to convert harmful gases into less harmful gases before they are released into the air.

Definition

Catalyst

A substance that increases the rate of a reaction and is chemically unchanged at the end of the reaction.

  1. A catalytic converter contains a ceramic honeycomb coated with a thin layer of transition metal catalysts, such as platinum and rhodium.
  2. The honeycomb gives the catalyst a very large surface area, so the exhaust gases make frequent contact with it and react quickly.
  3. The converter works best once it is hot, so it removes pollutants most effectively after the engine has warmed up.
  4. On the surface of the catalyst, harmful gases react to form less harmful gases.
  5. Nitrogen monoxide reacts with carbon monoxide to form nitrogen and carbon dioxide: 2CO+2NO→2CO2+N2\mathrm{2CO + 2NO \rightarrow 2CO_{2} + N_{2}}2CO+2NO→2CO2​+N2​.
  6. This single reaction removes two pollutants at once: carbon monoxide, which is toxic, and nitrogen monoxide, which causes acid rain.
  7. In this reaction nitrogen monoxide is reduced, because it loses oxygen, and carbon monoxide is oxidised, because it gains oxygen.
  8. Nitrogen dioxide is removed in the same way: 2NO2+4CO→N2+4CO2\mathrm{2NO_{2} + 4CO \rightarrow N_{2} + 4CO_{2}}2NO2​+4CO→N2​+4CO2​.
  9. The products, nitrogen and carbon dioxide, are not toxic, although the carbon dioxide still adds to global warming.
Example

Balancing the catalytic converter equation

  • Start from the formulae of the reactants and products.
CO+NO→CO2+N2 \mathrm{CO + NO \rightarrow CO_{2} + N_{2}} CO+NO→CO2​+N2​
  • There are two nitrogen atoms on the right, so place a 2 in front of NO\mathrm{NO}NO.
CO+2NO→CO2+N2 \mathrm{CO + 2NO \rightarrow CO_{2} + N_{2}} CO+2NO→CO2​+N2​
  • There are now three oxygen atoms on the left and two on the right, so place a 2 in front of both CO\mathrm{CO}CO and CO2\mathrm{CO_{2}}CO2​, which balances carbon and oxygen together.
2CO+2NO→2CO2+N2 \mathrm{2CO + 2NO \rightarrow 2CO_{2} + N_{2}} 2CO+2NO→2CO2​+N2​
  • Each side now has two carbon atoms, four oxygen atoms and two nitrogen atoms.

The symbol equation for photosynthesis

Definition

Photosynthesis

The reaction between carbon dioxide and water to produce glucose and oxygen, in the presence of chlorophyll and using energy from light.

  1. The symbol equation for photosynthesis is 6CO2+6H2O→C6H12O6+6O2\mathrm{6CO_{2} + 6H_{2}O \rightarrow C_{6}H_{12}O_{6} + 6O_{2}}6CO2​+6H2​O→C6​H12​O6​+6O2​.
  2. Glucose has the formula C6H12O6\mathrm{C_{6}H_{12}O_{6}}C6​H12​O6​, so six molecules of carbon dioxide are needed to provide its six carbon atoms.
  3. Six molecules of water provide the twelve hydrogen atoms in each glucose molecule.
  4. The oxygen atoms that are not used to make glucose are released as six molecules of oxygen gas.
  5. For every six molecules of carbon dioxide taken in, six molecules of oxygen are given out.
Example

Checking the photosynthesis equation

6CO2+6H2O→C6H12O6+6O2 \mathrm{6CO_{2} + 6H_{2}O \rightarrow C_{6}H_{12}O_{6} + 6O_{2}} 6CO2​+6H2​O→C6​H12​O6​+6O2​
  • Carbon: 666 atoms in 6CO2\mathrm{6CO_{2}}6CO2​ on the left and 666 atoms in C6H12O6\mathrm{C_{6}H_{12}O_{6}}C6​H12​O6​ on the right.
  • Hydrogen: 121212 atoms in 6H2O\mathrm{6H_{2}O}6H2​O on the left and 121212 atoms in C6H12O6\mathrm{C_{6}H_{12}O_{6}}C6​H12​O6​ on the right.
  • Oxygen: 12+6=1812 + 6 = 1812+6=18 atoms on the left and 6+12=186 + 12 = 186+12=18 atoms on the right.
  • Every element has the same number of atoms on each side, so the equation is balanced.
Exam technique

Explaining the greenhouse effect

  • Describe the energy as thermal energy or infrared radiation emitted by the Earth's surface.
  • Use the sequence: thermal energy is absorbed by greenhouse gases, then emitted back towards the Earth, so less thermal energy is lost to space.
  • Name the greenhouse gases as carbon dioxide and methane.
  • For the formation of oxides of nitrogen, state that the high temperature in the engine makes nitrogen and oxygen from the air react.
  • Give balanced equations with correct formulae, such as 2CO+2NO→2CO2+N2\mathrm{2CO + 2NO \rightarrow 2CO_{2} + N_{2}}2CO+2NO→2CO2​+N2​.
Common Mistake
  • Do not say that greenhouse gases trap sunlight or ultraviolet light coming from the Sun, because they absorb the thermal energy emitted by the Earth's surface.
  • Do not link the greenhouse effect to holes in the ozone layer, because the two are separate problems.
  • Do not say that oxides of nitrogen come from nitrogen in the fuel, because the nitrogen comes from the air.
  • Do not say that a catalytic converter removes carbon dioxide, because carbon dioxide is one of its products.
Self review
  • Name two greenhouse gases.
  • Explain how greenhouse gases reduce the loss of thermal energy to space.
  • Why do nitrogen and oxygen react inside a car engine but not in the air around us?
  • Write the equation for the reaction between carbon monoxide and nitrogen monoxide in a catalytic converter.
  • State the symbol equation for photosynthesis.
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10.3.3 Greenhouse gases and catalytic converters Revision Guide

  1. IGCSE
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Revision notes for CIE IGCSE Chemistry 10.3.3 Greenhouse gases and catalytic converters: explanations and worked examples.

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