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9.3.1 Alloys and their uses

What an alloy is

Definition

Alloy

A mixture of a metal with one or more other elements.

  1. An alloy is made by melting a metal, mixing one or more other elements into it, and then letting the mixture cool and solidify.
  2. The added elements can be other metals, such as the zinc in brass, or non-metals, such as the carbon in steel.
  3. An alloy is a mixture, not a compound, because the elements in it are not chemically combined in a fixed ratio.
  4. Because it is a mixture, the amounts of each element can be changed to give an alloy with exactly the properties that are needed.
  5. Many of the "metals" you use every day are really alloys, including the steel in cars and bridges and the gold in most jewellery, which is mixed with copper or silver.

Brass and stainless steel

Definition

Brass

An alloy made by mixing copper with zinc.

Definition

Stainless steel

An alloy of iron with other elements such as chromium, nickel and carbon that is hard and resists rusting.

  1. Brass is an alloy of copper and zinc.
    1. Brass is harder than pure copper, it resists corrosion and it has an attractive gold colour.
    2. Brass is used for door handles, the pins of electrical plugs and musical instruments such as trumpets.
  2. Stainless steel is an alloy of iron with other elements such as chromium, nickel and carbon.
    1. Stainless steel is much harder than pure iron and it does not rust in ordinary use.
    2. Stainless steel is used for cutlery, kitchen sinks, saucepans and surgical instruments.

Why alloys are more useful

Definition

Hardness

The ability of a material to resist being scratched or dented.

Definition

Strength

The ability of a material to withstand a force without breaking or changing shape.

  1. Alloys can be harder and stronger than the pure metals they are made from.
  2. Many pure metals are too soft for everyday use, because pure iron bends easily and pure gold scratches easily.
  3. Turning a metal into an alloy gives a material that keeps its shape under force and resists wear, so alloys are more useful than pure metals for most jobs.
  4. Some alloys also gain other useful properties, such as the resistance to rusting of stainless steel.
  5. This is why far more alloys than pure metals are used to make everyday objects.

Uses of alloys

  1. The use of an alloy is explained by its physical properties, in the same way as the uses of pure metals.
  2. Stainless steel is used for cutlery because it is hard, so knives and forks do not bend, dent or scratch easily.
  3. Stainless steel is also used for cutlery because it is resistant to rusting, so it stays clean and shiny after being washed many times.
  4. Pure iron would make poor cutlery, because it is softer and it rusts in contact with water and air.
  5. Brass is used for plug pins because it conducts electricity and is harder than copper, so the pins do not bend when they are pushed into a socket.
Exam technique

Explaining the use of an alloy

  • State the property and then link it to the job, for example "stainless steel is hard, so cutlery does not bend".
  • For stainless steel cutlery, give both hardness and resistance to rusting.
  • When you describe an alloy, use the word mixture, because calling an alloy a compound is a common way to lose the mark.

Identifying alloys from diagrams

  1. Structure diagrams show each atom as a circle, so you can tell a pure metal from an alloy by comparing the circles.
  2. A pure metal is drawn as identical circles packed in regular rows, because all of its atoms are the same size.
  3. An alloy is drawn as rows of one kind of circle with some circles of a different size scattered among them.
  4. The different circles may be larger or smaller than the main metal atoms, and they either replace some of the metal atoms or sit in the gaps between them.
  5. A diagram showing separate groups of joined circles, with space between the groups, represents a substance made of molecules, not an alloy.
  6. The feature that identifies an alloy is two or more types of atom mixed within one closely packed metal structure.
Example

Reading four structure diagrams

  • Diagram A shows rows of identical circles in a regular pattern, so it represents a pure metal.
  • Diagram B shows the same rows with a few larger circles in place of some of the original ones, so it represents an alloy such as brass.
  • Diagram C shows pairs of joined circles with gaps between the pairs, so it represents a substance made of molecules.
  • Diagram D shows rows of large circles with small circles fitted into some of the gaps, so it represents an alloy such as steel, in which small carbon atoms sit among iron atoms.
Common Mistake
  • Do not describe an alloy as a compound, because its elements are mixed, not chemically bonded.
  • Do not say that an alloy contains only metals, because steel contains carbon, which is a non-metal.
  • Do not mix up hardness and strength, because hardness is resistance to scratching and denting, while strength is resistance to breaking under a force.
Self review
  • What is an alloy?
  • Which two metals are mixed to make brass?
  • Name three elements, other than iron, that can be present in stainless steel.
  • Give two properties that make stainless steel suitable for cutlery.
  • How can you tell from a structure diagram that a substance is an alloy?
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9.3.1 Alloys and their uses Revision Guide

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Revision notes for CIE IGCSE Chemistry 9.3.1 Alloys and their uses: explanations and worked examples.

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