Energetics

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Question 6
Medium

A student carries out an experiment to investigate the temperature change during the chemical reaction between dilute nitric acid and potassium hydroxide solution.

The diagram shows the experimental setup used by the student:

Experimental setup for measuring temperature change during neutralization. A vertical metal stand supports an adjustable clamp holding a long, narrow graduated glass tube (a burette) with a tap at the bottom. The tap is positioned directly above a glass beaker. Inside the glass beaker is a liquid, and a glass thermometer with a bulb at the bottom is resting at an angle inside the beaker to measure temperature. Three labeling lines are shown: Line A points to the vertical metal rod with its heavy base; Line B points to the graduated glass tube; Line C points to the internal glass thermometer.

a.

(i) Identify the equipment labeled A, B, and C in the diagram. (ii) State one modification the student can make to this apparatus to obtain a more accurate measurement of the temperature change.

[4]
b.

The student adds the potassium hydroxide solution, 4 cm34\text{ cm}^34 cm3 at a time, to the dilute nitric acid in the beaker. The table below shows the recorded temperatures.

Volume of potassium hydroxide solution added (cm3\text{cm}^3cm3)Temperature (∘C^\circ\text{C}∘C)
016.5
418.5
821.0
1223.5
1625.0
2023.5
2421.5

(i) Describe how the temperature of the reaction mixture changes as the potassium hydroxide solution is added. (ii) Explain how these results demonstrate that the reaction is exothermic.

[2]
c.

The activation energy for this neutralization reaction is relatively low. State the meaning of the term activation energy.

[1]

Energetics Questions

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