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2.1.2 Ionic bonding

Ionic bonding: electrons transfer from metals to non-metals

Definition

Outer shell

The highest occupied electron shell of an atom, containing the electrons involved when the atom forms an ion.

  1. An ionic bond forms when a metal atom reacts with a non-metal atom.
  2. An ion is a charged particle formed when an atom gains or loses electrons.
  3. The metal atom loses the electrons in its outer shell and becomes a positively charged ion.
  4. The non-metal atom gains those transferred electrons and becomes a negatively charged ion.
  5. The number of protons never changes, so the charge comes only from the electrons gained or lost.
    1. For example, sodium loses one electron to form Na+\text{Na}^{+}Na+ while chlorine gains one to form Cl−\text{Cl}^{-}Cl−.
Key Idea
  • Metals lose electrons and form positive ions.
  • Non-metals gain electrons and form negative ions.
  • Electrons are transferred, not shared, during ionic bonding.

Group number: it predicts the charge on each ion

  1. Group 1 metals
    1. A Group 1 atom has one electron in its outer shell.
    2. It loses one electron and forms an ion with a charge of 1+1+1+, such as Na+\text{Na}^{+}Na+.
  2. Group 2 metals
    1. A Group 2 atom has two electrons in its outer shell.
    2. It loses two electrons and forms an ion with a charge of 2+2+2+, such as Mg2+\text{Mg}^{2+}Mg2+.
  3. Group 6 non-metals
    1. A Group 6 atom has six electrons in its outer shell.
    2. It gains two electrons and forms an ion with a charge of 2−2-2−, such as O2−\text{O}^{2-}O2−.
  4. Group 7 non-metals
    1. A Group 7 atom has seven electrons in its outer shell.
    2. It gains one electron and forms an ion with a charge of 1−1-1−, such as Cl−\text{Cl}^{-}Cl−.
  5. For Group 1 and Group 2 metals, the positive charge equals the group number.
  6. For Group 6 and Group 7 non-metals, subtract the group number from eight to find the size of the negative charge.
Common Mistake
  • Do not give a Group 6 ion a charge of 6−6-6− or a Group 7 ion a charge of 7−7-7−.
  • The charge shows the number of electrons gained or lost, not the number of outer-shell electrons in the original atom.
  • Write the charge as Mg2+\text{Mg}^{2+}Mg2+ rather than Mg+2\text{Mg}^{+2}Mg+2.

Noble-gas structures: electron transfer produces full outer shells

Definition

Electronic structure

The arrangement of electrons in the electron shells of an atom or ion.

  1. The noble gases in Group 0 have full outer electron shells, which makes them very stable.
  2. Ions formed by Group 1, 2, 6 and 7 elements end up with the electronic structure of a noble gas.
  3. A Group 1 or Group 2 atom reaches this structure by losing its incomplete outer shell.
  4. A Group 6 or Group 7 atom reaches this structure by gaining enough electrons to fill its outer shell.
  5. The element does not turn into a noble gas, because its number of protons stays the same.
Example
  • Sodium changes from 2,8,12,8,12,8,1 to 2,82,82,8 when it forms Na+\text{Na}^{+}Na+, giving it the electronic structure of neon.
  • Chlorine changes from 2,8,72,8,72,8,7 to 2,8,82,8,82,8,8 when it forms Cl−\text{Cl}^{-}Cl−, giving it the electronic structure of argon.
  • Magnesium changes from 2,8,22,8,22,8,2 to 2,82,82,8 when it forms Mg2+\text{Mg}^{2+}Mg2+.
  • Oxygen changes from 2,62,62,6 to 2,82,82,8 when it forms O2−\text{O}^{2-}O2−.

Dot-and-cross diagrams: they show where each outer electron came from

Definition

Dot-and-cross diagram

A diagram that uses dots and crosses to show the outer-shell electrons from different atoms and any electrons transferred between them.

  1. Begin by drawing the correct number of outer-shell electrons for each metal atom and non-metal atom.
  2. Use dots for one element and crosses for the other so you can track where each electron started.
  3. Transfer the metal atom's outer-shell electrons to the non-metal atom.
  4. Check that every metal atom loses the correct number of electrons and every non-metal atom gains the correct number.
  5. Draw each resulting ion inside square brackets.
  6. Write the ion's charge outside the brackets at the top right.
  7. Finally, check that the non-metal ion has a full outer shell and that every transferred electron appears only once.
Common Mistake
  • Dots and crosses show the source of each electron, not whether an ion is positive or negative.
  • You may swap which element uses dots and which uses crosses, but you must use the symbols consistently.
  • Do not leave the transferred electron on the metal atom or draw the same electron on both ions.
  • Do not omit the square brackets or ion charges from the completed diagram.

Four group pairings: the same charge rules build every required diagram

Definition

Ionic compound

A compound formed from positively charged ions and negatively charged ions with no overall electrical charge.

  1. Group 1 metal with Group 7 non-metal, such as NaCl\text{NaCl}NaCl
    1. One metal atom transfers one electron to one non-metal atom, giving one 1+1+1+ ion and one 1−1-1− ion.
  2. Group 1 metal with Group 6 non-metal, such as Na2O\text{Na}_2\text{O}Na2​O
    1. Two metal atoms each transfer one electron to one non-metal atom, giving two 1+1+1+ ions and one 2−2-2− ion.
  3. Group 2 metal with Group 7 non-metal, such as MgCl2\text{MgCl}_2MgCl2​
    1. One metal atom transfers one electron to each of two non-metal atoms, giving one 2+2+2+ ion and two 1−1-1− ions.
  4. Group 2 metal with Group 6 non-metal, such as MgO\text{MgO}MgO
    1. One metal atom transfers two electrons to one non-metal atom, giving one 2+2+2+ ion and one 2−2-2− ion.
  5. In every ionic compound the positive and negative charges balance to give no overall charge.
  6. You only need dot-and-cross diagrams for Group 1 and 2 metals combined with Group 6 and 7 non-metals at this level.
Self review
  • What happens to the outer-shell electrons when a metal atom reacts with a non-metal atom?
  • What charges are formed by elements in Groups 1, 2, 6 and 7?
  • Why do the resulting ions have the electronic structures of noble gases?
  • What must you include around each ion in a completed dot-and-cross diagram?
  • Why are two chloride ions needed for each magnesium ion in MgCl2\text{MgCl}_2MgCl2​?

Recap questions

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An ion has 17 protons and 18 electrons. What is its charge?

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An atom is normally neutral because it has an equal number of positive protons and negative electrons. However, atoms are most stable when they have a full outer shell of electrons.

To achieve this stable state, atoms will lose or gain electrons. This forms an ion, which is a charged particle where the balance between protons and electrons is lost.

Cations are positively charged ions formed when an atom (usually a metal) loses electrons; remember: Cations are pawsitive! Anions are negatively charged ions formed when an atom (usually a non-metal) gains electrons; think: Anion = A Negative Ion.

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The formula of lead(IV) oxide is PbO2\text{PbO}_2PbO2​. Deduce the charge of the lead ion in lead(IV) oxide.

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In a neutral atom, how do protons and electrons compare?

Ionic bonding Revision Guide

  1. GCSE
  2. /Chemistry
  3. /Ionic bonding

Revision notes for Edexcel GCSE Chemistry Ionic bonding. Open the guide for explanations and worked examples. Written against the Edexcel GCSE Chemistry (1CH0) specification, so the content matches what's examinable rather than general Chemistry background.

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