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7.3 Group 0

7.3 Group 0

7.3.1 The noble gases

A full outer shell makes the noble gases inert

Definition

Noble gas

An element in Group 0 of the periodic table, which has a full outer shell of electrons.

Definition

Inert

Describes a substance that does not readily take part in chemical reactions.

  1. Helium, neon, argon, krypton and xenon all have a full outer shell of electrons.
  2. A full shell is eight electrons, except for helium, which is full with two.
  3. Reacting means gaining, losing or sharing electrons to reach a full shell.
  4. A noble gas already has one, so it has nothing to gain from reacting.
  5. They are therefore inert, and they exist as single atoms rather than as molecules.
Key Idea

Other elements react so as to reach the full outer shell a noble gas already has.

Uses that depend on being inert

  1. Argon fills filament light bulbs, where it stops the hot filament burning away.
  2. Argon also shields the weld in arc welding, keeping air away from the hot metal.
  3. Helium and argon protect delicate objects in storage from reacting with air.
  4. An unreactive gas is chosen wherever a reaction with oxygen or nitrogen would cause damage.
  5. Air would not do the job, because its oxygen reacts with hot or exposed material.
Example
  • Filament lamp: argon, because it will not react with the glowing filament.
  • Welding: argon, because it keeps oxygen away from the molten metal.

Uses that depend on low density and non-flammability

  1. Helium has a very low density, so a balloon filled with it rises.
  2. Helium is also non-flammable, which is why it replaced hydrogen in airships.
  3. Hydrogen is lighter still, but it burns, which made it dangerous.
  4. Neon glows red-orange when a current passes through it, which is used in display signs.
  5. Each use is matched to a property, so the reason for the choice can always be named.
Common Mistake

Helium is chosen over hydrogen for safety, not because it is lighter.

The trend in physical properties down the group

  1. Boiling points rise steadily down the group, from helium at the top.
  2. Helium boils at about −269 ∘C-269\ ^{\circ}\text{C}−269 ∘C, the lowest of any element.
  3. Density also rises down the group, so helium is the least dense and radon the most.
  4. All the noble gases are gases at room temperature, despite the rise in boiling point.
  5. The rise follows the same reason as in Group 7: larger atoms attract one another more strongly.
Note

These are atoms, not molecules, so the attractions being overcome act between single atoms.

Predicting the properties of other noble gases

  1. A gas lower in the group has a higher boiling point and a higher density than one above it.
  2. Krypton therefore has a higher boiling point than argon and a lower one than xenon.
  3. Radon, at the bottom, has the highest boiling point and the greatest density.
  4. Every one of them stays inert, because they all have a full outer shell.
  5. A prediction is made by placing the element in the group and reading the neighbouring values.
Self review
  • Why are the noble gases chemically inert?
  • Why is helium full with only two outer electrons?
  • Give a use of argon and the property it depends on.
  • Why was helium used in airships instead of hydrogen?
  • Predict how the density of krypton compares with that of argon.

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Group 0 noble gases in top-to-bottom order, with atoms increasing in size, downward trends in boiling point and density, and electron-shell diagrams showing full shells in helium and neon The Group 0 elements are called the noble gases. Helium, neon, argon, krypton, xenon and radon all have a full outer shell of electrons.

A full outer shell usually contains eight electrons. Helium is an exception because its only shell is full with two electrons.

The noble gases are inert, meaning that they do not readily take part in chemical reactions. They are also monatomic, so they exist as single atoms rather than molecules.

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Group 0 elements are called

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Why are noble gases chemically inert?

7.3 Group 0 Revision Guide

  1. GCSE
  2. /Chemistry
  3. /7.3 Group 0

Revision notes for Edexcel GCSE Chemistry 7.3 Group 0: explanations and worked examples on 7.3.1 The noble gases.

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