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2.4.2 Uses of nanoparticles

Nanoparticle applications: the same material can do very different jobs

Definition

Nanoparticle

A particle between 1 nm1\ \text{nm}1 nm and 100 nm100\ \text{nm}100 nm in size.

Definition

Nanoparticulate material

A material made from or containing nanoparticles.

  1. A nanoparticle is a tiny particle, roughly 1 nm1\ \text{nm}1 nm to 100 nm100\ \text{nm}100 nm across (about 1×10−9 m1 \times 10^{-9}\ \text{m}1×10−9 m to 1×10−7 m1 \times 10^{-7}\ \text{m}1×10−7 m), so it behaves very differently from larger particles of the same substance.
  2. This means a nanoparticle can be well suited to a task that larger particles or other materials would do less effectively.
  3. Their very high surface area to volume ratio is the property behind many of these uses.
    1. A large fraction of their atoms sit on the surface, which is where reactions and interactions take place.
  4. A nanoparticulate material has useful applications in medicine, electronics, cosmetics and sun creams, deodorants and catalysts.
  5. Medicine
    1. Nanoparticles can help deliver drugs to particular cells and can be used in medical tests and imaging.
  6. Electronics
    1. Their tiny size lets manufacturers build very small electronic components and pack more into a device.
  7. Cosmetics and sun creams
    1. Nanoparticles can improve how a sun cream spreads and how well it blocks ultraviolet light without leaving a thick white layer.
  8. Deodorants
    1. Some nanoparticles act as active ingredients that reduce the bacteria responsible for body odour.
  9. Catalysts
    1. Nanoparticle catalysts speed up reactions, and because so much of the material is exposed surface, only a small mass is needed.
Note
  • This is separate (triple) chemistry only and is not needed for the Combined Science course.
  • You do not need to memorise named nanoparticles or detailed properties for these applications.

Advantages: a benefit only counts when it fits the purpose

Definition

Catalyst

A substance that increases reaction rate without being used up by providing an alternative pathway with lower activation energy.

  1. An advantage must explain how the nanoparticle helps to meet the stated purpose.
  2. Supplied information may show that a nanoparticle improves performance, reduces the amount of material needed, or allows a smaller product to be made.
  3. A nanoparticle catalyst can increase the rate of reaction, which can make an industrial process faster or cheaper.
    1. Because so many of the atoms lie on the surface, a small mass provides a large number of active sites.
  4. Other information may reveal disadvantages, such as a higher cost or limited evidence about safety.
  5. The most useful property depends on the purpose, so nanoparticles are not automatically the best choice.
Example
  • Given information: a nanoparticle sun cream gives longer-lasting protection using less material, but costs more and its effects on aquatic organisms are uncertain.
  • Supported judgement: it has clear performance advantages, but more evidence about environmental risk is needed before calling it the better choice.

Possible risks: small particles may open new routes to harm

Definition

Risk

The possibility that something will cause harm, together with how serious that harm could be.

  1. Using nanoparticles may carry both health risks and environmental risks.
  2. Some nanoparticles can enter the body if they are breathed in or swallowed.
  3. Once inside, they may interact with cells and tissues differently from larger particles of the same material.
  4. Their long-term effects are often uncertain because many nanoparticle applications are still relatively new.
  5. Nanoparticles released into the environment could enter water or soil and affect living organisms.
  6. The level of risk depends on the material, the amount present and the type of exposure.
  7. Different nanoparticles have different properties, so evidence about one cannot be assumed to apply to all of them.
Common Mistake
  • Do not claim that all nanoparticles are dangerous, because a risk is a possibility of harm, not proof that harm will happen.
  • Explain a possible route to harm, such as inhalation followed by contact with body cells, rather than just writing that nanoparticles are unsafe.

Evaluation: a justified judgement balances evidence and uncertainty

Definition

Evaluate

To use evidence to consider advantages, disadvantages and uncertainty before reaching a supported judgement.

  1. Identify the purpose
    1. State clearly what the nanoparticulate material must do.
  2. Select relevant evidence
    1. Use the supplied information about performance, cost, safety and environmental effects.
  3. Compare advantages and disadvantages
    1. Explain how each piece of evidence supports or challenges the proposed use.
  4. Consider uncertainty
    1. Check whether the evidence about short-term and long-term risks is reliable.
  5. Reach a judgement
    1. Decide whether the advantages outweigh the disadvantages for the specified purpose.
    2. Support the conclusion with evidence from the information provided.
Note
  • In an evaluate question, use evidence for both advantages and disadvantages before reaching a supported conclusion.
  • Avoid a memorised answer, because the best judgement depends on the purpose and the information in the question.

Research: new applications need performance and safety testing

  1. New applications for nanoparticulate materials are an important area of research.
  2. Research can test whether a nanoparticle actually performs its proposed job effectively.
  3. It can also investigate possible effects on human health and the environment.
  4. A useful application may still have disadvantages, so both performance and risk must be considered together.
  5. Conclusions may change as researchers collect more evidence about long-term effects.
Self review
  • Name four areas in which nanoparticles have applications.
  • What makes an advantage relevant when you evaluate a nanoparticle application?
  • Explain one possible health risk associated with nanoparticles.
  • What should a supported conclusion in an evaluation compare?
  • Why is further research needed into new nanoparticle applications?
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A nanoparticle is a particle between 1 nm1 \, \text{nm}1nm and 100 nm100 \, \text{nm}100nm in size. This is approximately 1×10−9 m1 \times 10^{-9} \, \text{m}1×10−9m to 1×10−7 m1 \times 10^{-7} \, \text{m}1×10−7m.

A nanoparticulate material is made from or contains nanoparticles. Nanoparticles can behave differently from larger particles of the same substance, so they can be useful for particular purposes.

Their very high surface area to volume ratio is important. A large fraction of their atoms are at the surface, where reactions and interactions take place.

Comparison of one large cube and eight smaller cubes with the same total volume, showing that smaller particles have more exposed surface

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What size range defines a nanoparticle?

2.4.2 Uses of nanoparticles Revision Guide

  1. GCSE
  2. /Chemistry
  3. /2.4.2 Uses of nanoparticles

Revision notes for AQA GCSE Chemistry 2.4.2 Uses of nanoparticles. Open the guide for explanations and worked examples. Written against the AQA GCSE Chemistry (8462) specification, so the content matches what's examinable rather than general Chemistry background.

Revision guides