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4.2.4 The pH scale and neutralisation

The pH scale measures how acidic or alkaline a solution is

Definition

pH scale

A scale running from 0 to 14 that shows how acidic or alkaline a solution is.

Definition

Hydrogen ion

A positively charged ion, H+\text{H}^{+}H+, produced by acids in aqueous solution.

  1. The pH scale runs from 0 to 14 and measures acidity.
  2. A solution with pH below 7 is acidic, pH 7 is neutral, and pH above 7 is alkaline.
  3. Acids produce hydrogen ions, H+\text{H}^{+}H+, in solution; the more hydrogen ions, the lower the pH.
  4. Alkalis produce hydroxide ions, OH−\text{OH}^{-}OH−, in solution; the more hydroxide ions, the higher the pH.
Key Idea
  • Lower pH means a higher hydrogen ion concentration and a stronger acidity.
  • Higher pH means a higher hydroxide ion concentration and a stronger alkalinity.

Measuring pH: universal indicator or a pH probe

Definition

Universal indicator

A mixture of indicators that changes colour across the pH scale and allows the approximate pH of a solution to be estimated.

  1. Universal indicator changes through a range of colours and is matched to a chart to estimate pH.
  2. It gives only an approximate whole-number pH, red for strong acid through green for neutral to purple for strong alkali.
  3. A pH probe connected to a meter gives a precise numerical pH.
  4. A probe is more accurate than an indicator and avoids judging colours by eye.
Exam technique
  • If a question wants a precise pH, choose a pH probe; if it wants a quick estimate, choose universal indicator.
  • Universal indicator is unsuitable for accurate work because its colour change is gradual and hard to judge.

Neutralisation makes water from hydrogen and hydroxide ions

Definition

Hydroxide ion

A negatively charged group of atoms with the formula OH−\text{OH}^-OH− that is present in metal hydroxides.

Definition

Neutralisation

The reaction of an acid with a base in which hydrogen ions and hydroxide ions combine to form water.

  1. In neutralisation, hydrogen ions from the acid react with hydroxide ions from the alkali.
  2. H+(aq)+OH−(aq)→H2O(l)\text{H}^{+}(aq) + \text{OH}^{-}(aq) \rightarrow \text{H}_2\text{O}(l)H+(aq)+OH−(aq)→H2​O(l)
  3. As the ions combine, the pH moves towards 7 and the solution becomes neutral at the end point.
  4. This ionic equation is the same for any strong acid neutralised by any strong alkali.
Self review
  • What is the pH of a neutral solution?
  • Which ion do acids produce in solution, and which ion do alkalis produce?
  • Why is a pH probe more accurate than universal indicator?
  • Write the ionic equation for neutralisation.
  • What happens to the pH as an acid is neutralised by an alkali?
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pH scale from 0 to 14 showing acidic, neutral, and alkaline regions; indicator colours; ion concentration trends; and methods for measuring pH

The pH scale runs from 0 to 14 and shows how acidic or alkaline a solution is. Values below 7 are acidic, pH 7 is neutral, and values above 7 are alkaline.

Acids produce hydrogen ions, H+\text{H}^{+}H+, in aqueous solution. Alkalis produce hydroxide ions, OH−\text{OH}^{-}OH−, in aqueous solution.

A lower pH indicates a higher concentration of H+\text{H}^{+}H+ and stronger acidity. A higher pH indicates a higher concentration of OH−\text{OH}^{-}OH− and stronger alkalinity.

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What range does the pH scale use?

4.2.4 The pH scale and neutralisation Revision Guide

  1. GCSE
  2. /Chemistry
  3. /4.2.4 The pH scale and neutralisation

Revision notes for AQA GCSE Chemistry 4.2.4 The pH scale and neutralisation. Open the guide for explanations and worked examples. Written against the AQA GCSE Chemistry (8462) specification, so the content matches what's examinable rather than general Chemistry background.

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