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10.4.1a The Haber process

The Haber process makes ammonia for fertilisers

Definition

Haber process

An industrial process that reacts nitrogen with hydrogen under controlled conditions to manufacture ammonia.

Definition

Ammonia

A compound of nitrogen and hydrogen with the formula NH₃.

  1. The Haber process manufactures ammonia, NH3\text{NH}_3NH3​, on an industrial scale.
  2. Ammonia is used to make nitrogen-based fertilisers, which raise crop yields.
  3. Producing ammonia this way is vital for growing enough food for a rising population.
Key Idea
  • The Haber process turns two abundant gases into ammonia.
  • That ammonia is the starting point for nitrogen fertilisers.

Raw materials: nitrogen from the air, hydrogen from natural gas

  1. Nitrogen is obtained from the air, which is about 78% nitrogen.
  2. Hydrogen is obtained from natural gas, which is mainly methane.
  3. The two gases are purified before they enter the reactor.
Note
  • Both raw materials are cheap and readily available, which makes large-scale production possible.
  • The purified nitrogen and hydrogen are mixed in a ratio of one to three, matching the equation.

The reaction conditions

Definition

Catalyst

A substance that increases reaction rate without being used up by providing an alternative pathway with lower activation energy.

  1. The purified gases are passed over an iron catalyst.
  2. The reactor runs at a temperature of about 450 degrees Celsius.
  3. It also runs at a high pressure of about 200 atmospheres.
  4. The reaction is reversible: N2+3H2⇌2NH3\text{N}_2 + 3\text{H}_2 \rightleftharpoons 2\text{NH}_3N2​+3H2​⇌2NH3​.
Example
  • The iron catalyst speeds up the reaction so ammonia forms quickly enough to be useful.
  • The high pressure squeezes the gases together, which helps more ammonia form.

Separating and recycling the gases

  1. The reaction never uses up all the nitrogen and hydrogen, so the mixture leaving the reactor contains all three gases.
  2. The mixture is cooled so that the ammonia condenses into a liquid and is removed.
  3. The unreacted nitrogen and hydrogen are recycled back into the reactor.
    1. Recycling means very little of the raw material is wasted.
Exam technique
  • Learn the conditions to recall: an iron catalyst, about 450 degrees Celsius and about 200 atmospheres.
  • Write the equation with the reversible arrow: N2+3H2⇌2NH3\text{N}_2 + 3\text{H}_2 \rightleftharpoons 2\text{NH}_3N2​+3H2​⇌2NH3​.

What the ammonia is used for

  1. Most of the ammonia is used to make nitrogen-based fertilisers, such as ammonium salts.
  2. Ammonia is also used to manufacture nitric acid.
  3. These products support farming, so the Haber process underpins the world's food supply.
Self review
  • What two gases are the raw materials for the Haber process, and where does each come from?
  • State the catalyst, temperature and pressure used in the Haber process.
  • Write the balanced symbol equation for the reaction, including the reversible arrow.
  • How are the ammonia and the unreacted gases separated?
  • Give one use of the ammonia made in the Haber process.
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Flowchart of the Haber process showing nitrogen from air and hydrogen from natural gas entering a reactor, ammonia being separated, and unreacted gases being recycled

The Haber process is an industrial process used to manufacture ammonia, NH3\text{NH}_3NH3​. Ammonia is needed to make nitrogen-based fertilisers, which help increase crop yields and support the world's food supply.

The raw materials are nitrogen and hydrogen. Nitrogen is obtained from air, which is about 78% nitrogen, while hydrogen is obtained mainly from natural gas, which contains methane.

The purified gases react according to the balanced reversible equation:

N2+3H2⇌2NH3 \text{N}_2 + 3\text{H}_2 \rightleftharpoons 2\text{NH}_3 N2​+3H2​⇌2NH3​

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Ammonia, NH3\text{NH}_3NH3​.

10.4.1a The Haber process Revision Guide

  1. GCSE
  2. /Chemistry
  3. /10.4.1a The Haber process

Revision notes for AQA GCSE Chemistry 10.4.1a The Haber process: explanations and worked examples.

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