The Haber process makes ammonia for fertilisers
Haber process
An industrial process that reacts nitrogen with hydrogen under controlled conditions to manufacture ammonia.
Ammonia
A compound of nitrogen and hydrogen with the formula NH₃.
- The Haber process manufactures ammonia, NH3\text{NH}_3NH3, on an industrial scale.
- Ammonia is used to make nitrogen-based fertilisers, which raise crop yields.
- Producing ammonia this way is vital for growing enough food for a rising population.
- The Haber process turns two abundant gases into ammonia.
- That ammonia is the starting point for nitrogen fertilisers.
Raw materials: nitrogen from the air, hydrogen from natural gas
- Nitrogen is obtained from the air, which is about 78% nitrogen.
- Hydrogen is obtained from natural gas, which is mainly methane.
- The two gases are purified before they enter the reactor.
- Both raw materials are cheap and readily available, which makes large-scale production possible.
- The purified nitrogen and hydrogen are mixed in a ratio of one to three, matching the equation.
The reaction conditions
Catalyst
A substance that increases reaction rate without being used up by providing an alternative pathway with lower activation energy.
- The purified gases are passed over an iron catalyst.
- The reactor runs at a temperature of about 450 degrees Celsius.
- It also runs at a high pressure of about 200 atmospheres.
- The reaction is reversible: N2+3H2⇌2NH3\text{N}_2 + 3\text{H}_2 \rightleftharpoons 2\text{NH}_3N2+3H2⇌2NH3.
- The iron catalyst speeds up the reaction so ammonia forms quickly enough to be useful.
- The high pressure squeezes the gases together, which helps more ammonia form.
Separating and recycling the gases
- The reaction never uses up all the nitrogen and hydrogen, so the mixture leaving the reactor contains all three gases.
- The mixture is cooled so that the ammonia condenses into a liquid and is removed.
- The unreacted nitrogen and hydrogen are recycled back into the reactor.
- Recycling means very little of the raw material is wasted.
- Learn the conditions to recall: an iron catalyst, about 450 degrees Celsius and about 200 atmospheres.
- Write the equation with the reversible arrow: N2+3H2⇌2NH3\text{N}_2 + 3\text{H}_2 \rightleftharpoons 2\text{NH}_3N2+3H2⇌2NH3.
What the ammonia is used for
- Most of the ammonia is used to make nitrogen-based fertilisers, such as ammonium salts.
- Ammonia is also used to manufacture nitric acid.
- These products support farming, so the Haber process underpins the world's food supply.
- What two gases are the raw materials for the Haber process, and where does each come from?
- State the catalyst, temperature and pressure used in the Haber process.
- Write the balanced symbol equation for the reaction, including the reversible arrow.
- How are the ammonia and the unreacted gases separated?
- Give one use of the ammonia made in the Haber process.
