Synthetic and naturally occurring polymers (chemistry only)

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Question 10
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High-performance lower-limb prosthetic sockets must be both durable and comfortable for the user. They are often manufactured with a soft, lightweight poly(ethene) inner liner surrounded by a highly rigid, carbon-fibre reinforced polyester composite outer shell.

a.

The displayed structural formula of poly(ethene) is shown below:

[HH∣∣−C−C−∣∣HH]n\left[ \begin{array}{cc} \text{H} & \text{H} \\ | & | \\ -\text{C} & -\text{C}- \\ | & | \\ \text{H} & \text{H} \end{array} \right]_n​H∣−C∣H​H∣−C−∣H​​n​

An incomplete displayed structural formula of the monomer ethene is shown below:

HH  CC  HH\begin{array}{cc} \text{H} & \text{H} \\ \ \ \text{C} & \text{C} \\ \ \ \text{H} & \text{H} \end{array}H  C  H​HCH​

Complete the structural formula of the monomer ethene by describing the necessary bonds to connect all the atoms correctly.

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b.

The rigid outer shell of the prosthetic contains a polyester. Two monomers, X and Y, are reacted to make this polyester:

  • Monomer X: HO−□−OH\text{HO} - \square - \text{OH}HO−□−OH
  • Monomer Y: HOOC−□−COOH\text{HOOC} - \square - \text{COOH}HOOC−□−COOH

Name the functional group in monomer Y.

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c.

Monomers X and Y undergo condensation polymerisation to produce the polyester and a small molecule. Name this small molecule.

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d.

Explain, in terms of structure and bonding, why this polyester outer shell melts when it is heated.

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e.

The outer shell is a composite material containing carbon fibres embedded in a polyester resin matrix. Match each material to its correct role as either the matrix or the reinforcement:

  • Carbon fibres
  • Polyester
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f.

Suggest two physical or mechanical reasons why this tough, rigid composite outer shell is added to the soft poly(ethene) inner liner.

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Synthetic and naturally occurring polymers (chemistry only) Questions

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