2.2.2 State symbols in chemical equations
State symbols: each formula shows the physical state of the substance
State symbol
A symbol in a chemical equation that shows whether a substance is solid, liquid, gas or dissolved in water.
- A state symbol is a lower-case letter in brackets that shows the physical state of a substance in a chemical equation.
- State symbols let you tell apart solids, liquids, gases and substances dissolved in water.
- The correct state symbol depends on the substance and the conditions under which the reaction takes place.
- Write a state symbol immediately after the formula of each substance.
- State symbols give information about a substance but are not part of its chemical formula.
The four symbols distinguish the three states of matter from aqueous solutions
Aqueous solution
A mixture formed when a substance is dissolved in water.
- Solid, (s)(\text{s})(s)
- Use (s)(\text{s})(s) when the substance is a solid under the reaction conditions.
- Liquid, (l)(\text{l})(l)
- Use (l)(\text{l})(l) when the substance is a pure liquid.
- Gas, (g)(\text{g})(g)
- Use (g)(\text{g})(g) when the substance is a gas under the reaction conditions.
- Aqueous, (aq)(\text{aq})(aq)
- Use (aq)(\text{aq})(aq) when the substance is dissolved in water to form an aqueous solution.
- Do not use (l)(\text{l})(l) for a substance just because it is present in a solution.
- A pure liquid takes (l)(\text{l})(l), while a substance dissolved in water takes (aq)(\text{aq})(aq).
State symbols follow formulae, while coefficients stay at the front
Coefficient
A large whole number placed before a chemical formula to show the relative number of particles or moles in a balanced equation.
- Write each state symbol immediately after the formula it describes, such as O2(g)\text{O}_2(\text{g})O2(g) or MgO(s)\text{MgO}(\text{s})MgO(s).
- Write a coefficient before a formula when balancing an equation, such as 2Mg(s)2\text{Mg}(\text{s})2Mg(s).
- Include a state symbol for every reactant and product when a question asks for them.
- Keep the chemical formula unchanged when you add a state symbol.
- Burning magnesium uses solid magnesium and oxygen gas to make solid magnesium oxide.
- 2Mg(s)+O2(g)→2MgO(s)2\text{Mg}(\text{s}) + \text{O}_2(\text{g}) \rightarrow 2\text{MgO}(\text{s})2Mg(s)+O2(g)→2MgO(s)
- Neutralisation can involve two aqueous solutions making an aqueous salt and liquid water.
- HCl(aq)+NaOH(aq)→NaCl(aq)+H2O(l)\text{HCl}(\text{aq}) + \text{NaOH}(\text{aq}) \rightarrow \text{NaCl}(\text{aq}) + \text{H}_2\text{O}(\text{l})HCl(aq)+NaOH(aq)→NaCl(aq)+H2O(l)
Reaction conditions determine which state symbol is correct
- Use the information in the question to decide the physical state of each substance during the reaction.
- The same substance can have different state symbols under different conditions.
- Water at room temperature is written as H2O(l)\text{H}_2\text{O}(\text{l})H2O(l), while steam is written as H2O(g)\text{H}_2\text{O}(\text{g})H2O(g).
- Solid sodium chloride is written as NaCl(s)\text{NaCl}(\text{s})NaCl(s), while sodium chloride dissolved in water is written as NaCl(aq)\text{NaCl}(\text{aq})NaCl(aq).
- Do not assume every substance containing water is aqueous, because (aq)(\text{aq})(aq) means dissolved in water rather than mixed with water.
- A question may give the states directly through words such as solid, molten, gas or solution.
- If a substance is described as molten, it is a liquid and takes the symbol (l)(\text{l})(l).
A complete equation gives the correct state for every reactant and product
Reactant
A reactant is a substance that is changed or used up during a chemical reaction.
- Check that every formula has a state symbol when the question asks you to include them.
- Check that (aq)(\text{aq})(aq) is used only for a substance dissolved in water.
- Check that each symbol is lower case and enclosed in round brackets.
- Check that coefficients come before formulae and state symbols come after them.
- Check that the state symbols match the conditions described in the question.
- Which state symbol shows that a substance is a solid?
- What does the state symbol (aq)(\text{aq})(aq) mean?
- Where should a state symbol be placed in relation to a chemical formula?
- What is the difference between H2O(l)\text{H}_2\text{O}(\text{l})H2O(l) and H2O(g)\text{H}_2\text{O}(\text{g})H2O(g)?
- Which state symbol should be used for molten sodium chloride?
