Organic chemistry

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Question 3
Hard

This question is about polymers.

a.

Polyesters are condensation polymers. When the monomers react together, a small molecule is lost.

Name a small molecule that can be lost during the formation of a polyester.

[1]
b.

Poly(tetrafluoroethene) (PTFE) is an addition polymer produced from tetrafluoroethene.

Complete the structure of poly(tetrafluoroethene) in the polymerisation equation below:

An incomplete chemical equation for the formation of poly(tetrafluoroethene)

[3]
c.

Disposable take-away food containers can be made from:

  • expanded polystyrene
  • sugarcane bagasse (a natural plant fibre)
  • a mixture of recycled polystyrene and sugarcane bagasse

Recycled polystyrene is more durable and water-resistant than sugarcane bagasse.

A container made from a mixture of recycled polystyrene and sugarcane bagasse is more sustainable than using 100% brand new polystyrene or 100% sugarcane bagasse.

Suggest why.

[5]
d.

Surgical sutures (stitches) are used to hold body tissues together after surgery or injury. Some sutures are designed to dissolve inside the body, while others must be removed later.

The table below shows some properties of two polymer fibres used for surgical sutures.

PropertyPolyglycolic acid (PGA) (a polyester)Nylon (a polyamide)
Tensile strength in MPa\text{MPa}MPa800800800400400400
Biodegradability (in contact with body fluids)Hydrolysed and absorbed by body tissues within 60 to 90 daysHighly stable, does not break down over time
Flexibility and knot securityExcellent (knots stay tight and secure)Moderate (stiffer, knots can tend to slip open)
Tissue reaction / inflammationExtremely lowLow

Evaluate the suitability of polyglycolic acid (PGA) and nylon for use as surgical sutures.

[5]

Organic chemistry Questions

  1. GCSE
  2. /Chemistry
  3. /Organic chemistry