Identification of ions by chemical and spectroscopic means (chemistry only)

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Question 8
Medium

This question is about qualitative analysis and the identification of ions.

A student investigated a sample of calcium chloride solution and a sample of potassium sulfate solution.

The student carried out flame tests using the following method:

  1. Dip a clean metal wire into the calcium chloride solution.
  2. Place the wire into the hot, blue flame of a Bunsen burner.
  3. Record the flame colour produced.
  4. Without cleaning the wire, dip it directly into the potassium sulfate solution and repeat the flame test.
a.

State the flame colour produced by the calcium chloride solution.

[1]
b.

Potassium compounds produce a characteristic lilac flame. Explain why the student's method did not produce a distinct lilac flame colour when testing the potassium sulfate solution.

[2]
c.

In a separate set of tests, the student added sodium hydroxide solution dropwise until in excess to:

  • the calcium chloride solution
  • the potassium sulfate solution.

State the observations for both tests.

[2]
d.

To confirm the presence of halide ions in the calcium chloride solution, the student first acidified the sample with dilute nitric acid. Name the reagent that must be added next to show the presence of chloride ions.

[1]
e.

To test for the presence of sulfate ions in the potassium sulfate solution, the student first acidified the sample with dilute hydrochloric acid. Name the reagent added to show the presence of sulfate ions, and state the observation that indicates a positive result.

[2]

Identification of ions by chemical and spectroscopic means (chemistry only) Questions

  1. GCSE
  2. /Chemistry
  3. /Identification of ions by chemical and spectroscopic means (chemistry only)