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3.1.4 Chemical measurements

3.1.4 Chemical measurements

Every measurement carries some uncertainty

Definition

Measurement uncertainty

The estimated interval around a measured value within which the result is expected to lie.

  1. No measurement is ever perfectly exact, so every result has some uncertainty attached to it.
  2. The resolution of the equipment and small differences in how it is read both add to this uncertainty.
Key Idea

Repeating a measurement and comparing the results is how you judge how confident you can be in the value.

Repeat the reading, then take a mean

Definition

Repeated measurement

A measurement of the same quantity made again using the same method.

Definition

Mean

The value found by adding all the measurements and dividing by the number of measurements.

  1. Make several repeated measurements of the same quantity using the same method.
  2. Spot any anomalous result that is much larger or smaller than the rest and leave it out.
  3. Add the remaining results and divide by how many there are to find the mean.
    1. The mean is more reliable than any single reading because random errors partly cancel out.
Example
  • Four readings give 24.224.224.2, 24.324.324.3, 24.424.424.4 and 25.9 cm325.9\ \text{cm}^325.9 cm3.
  • The 25.9 cm325.9\ \text{cm}^325.9 cm3 value is anomalous, so it is left out.
  • The mean is 24.2+24.3+24.43=24.3 cm3\frac{24.2 + 24.3 + 24.4}{3} = 24.3\ \text{cm}^3324.2+24.3+24.4​=24.3 cm3.

The range shows how spread out the results are

Definition

Range

The difference between the highest and lowest values in a set of measurements.

  1. The range is the difference between the highest and lowest of the valid results.
  2. A smaller range means the results are more consistent, so you can trust the mean more.
Example

For the three valid readings above, the range is 24.4−24.2=0.2 cm324.4 - 24.2 = 0.2\ \text{cm}^324.4−24.2=0.2 cm3.

Estimate the uncertainty from the range about the mean

  1. You can estimate the uncertainty as plus or minus half of the range, measured about the mean.
  2. For the readings above this gives 24.3±0.1 cm324.3 \pm 0.1\ \text{cm}^324.3±0.1 cm3.
    1. Taking more careful repeats narrows the range and so reduces the uncertainty.
Exam technique
  • Always remove anomalous results before you calculate either the mean or the range.
  • Quote a measured value with its unit and its uncertainty, for example 24.3±0.1 cm324.3 \pm 0.1\ \text{cm}^324.3±0.1 cm3.

A distribution shows every value and how often it occurs

Definition

Distribution of results

The pattern showing the values obtained and how often each value occurs.

  1. Recording the distribution of results in a table or chart shows which values came up and how often.
  2. The spread of that distribution makes both the anomalies and the size of the uncertainty easy to see.
Self review
  • Why does every measurement have some uncertainty?
  • How do you calculate a mean from a set of repeated readings?
  • How do you work out the range of a set of results?
  • Readings of 18.418.418.4, 18.618.618.6 and 18.5 cm318.5\ \text{cm}^318.5 cm3 are collected; estimate the value and its uncertainty.
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No measurement is perfectly exact. Measurement uncertainty is the estimated interval around a measured value within which the result is expected to lie.

The resolution of the measuring equipment limits how precisely a value can be recorded. Small differences in how a person reads an instrument also contribute to uncertainty.

Repeating a measurement shows how consistent the results are. Results that cluster closely together give greater confidence in the measured value.

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Why does every measurement carry some uncertainty?

3.1.4 Chemical measurements Revision Guide

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  2. /Chemistry
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Revision notes for AQA GCSE Chemistry 3.1.4 Chemical measurements: explanations and worked examples.

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