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6.1.4 Catalysts

6.1.4 Catalysts

A catalyst speeds a reaction up without being used up

Definition

Catalyst

A substance that increases reaction rate without being used up by providing an alternative pathway with lower activation energy.

  1. A catalyst increases the rate of a reaction.
  2. It is not used up during the reaction, so its mass is the same at the end as at the start.
  3. Because it is not used up, a catalyst is not shown in the overall equation for the reaction.
  4. A small amount of catalyst can speed up the reaction of a large amount of reactant.
  5. Different reactions need different catalysts, so a catalyst is specific to the reaction it speeds up.

A catalyst works by lowering the activation energy

Definition

Activation energy

The minimum energy that reacting particles must have for a collision to result in a reaction.

Definition

Reaction profile

A diagram showing how the energy changes as reactants become products during a chemical reaction.

  1. A catalyst provides a different reaction pathway with a lower activation energy.
  2. More of the colliding particles now have enough energy to react.
  3. A larger fraction of collisions are therefore successful, so the reaction goes faster.
  4. On a reaction profile, the catalysed pathway has a lower peak than the uncatalysed one.
  5. The reactant and product energy levels are unchanged, so the overall energy change stays the same.

Reaction profile diagrams for catalysed and uncatalysed reactions. Both exothermic and endothermic profiles show that the catalysed pathway has a lower activation energy (Ea(cat)) compared to the uncatalysed pathway (Ea), while the energy levels of reactants and products remain the same.

Key Idea
  • A catalyst lowers the activation energy but does not change the overall energy change.
  • It speeds up the reaction without altering the amount of product formed.

Enzymes are the catalysts found in living things

  1. Enzymes are biological catalysts that speed up the reactions in living organisms.
  2. They are also used in industry, for example in making foods and washing powders.
Common Mistake
  • Do not write the catalyst as a reactant or a product in the equation.
  • A catalyst changes only the rate, not the amount of product you can make.
Exam technique
  • Say a catalyst gives a different pathway with a lower activation energy, not that it gives particles more energy.
  • If asked about a reaction profile, show a lower peak but the same reactant and product levels.
  • State that the catalyst is not used up, so it is left out of the overall equation.
Self review
  • What is a catalyst?
  • How does a catalyst increase the rate of a reaction?
  • Why is a catalyst not included in the overall equation?
  • What does a catalyst do to the activation energy and to the overall energy change?
  • What name is given to biological catalysts?
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A catalyst is a substance that increases the rate of a chemical reaction without being used up. It provides an alternative reaction pathway with a lower activation energy.

A catalyst can speed up the reaction of a large amount of reactant even when only a small amount is used. Different reactions need different catalysts, so catalysts are specific to the reactions they speed up.

Because the catalyst is not used up, its mass is the same at the end as at the start. It is therefore not included in the overall chemical equation.

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What effect does a catalyst have on reaction rate?

6.1.4 Catalysts Revision Guide

  1. GCSE
  2. /Chemistry
  3. /6.1.4 Catalysts

Revision notes for AQA GCSE Chemistry 6.1.4 Catalysts: explanations and worked examples.

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