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Bonding

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Question 5

Phenylphosphine (C6H5PH2\text{C}_6\text{H}_5\text{PH}_2C6​H5​PH2​) can be represented as ArPH2\text{ArPH}_2ArPH2​ and its protonated form, the phenylphosphonium ion ([C6H5PH3]+[\text{C}_6\text{H}_5\text{PH}_3]^+[C6​H5​PH3​]+), can be represented as [ArPH3]+[\text{ArPH}_3]^+[ArPH3​]+.

a.

Describe or draw the three-dimensional shapes around the phosphorus atom in ArPH2\text{ArPH}_2ArPH2​ and in [ArPH3]+[\text{ArPH}_3]^+[ArPH3​]+. Include any lone pairs on the phosphorus atom.

[4]
b.

State whether the H−P−H\text{H}-\text{P}-\text{H}H−P−H bond angle in ArPH2\text{ArPH}_2ArPH2​ is greater than, the same as, or smaller than that in [ArPH3]+[\text{ArPH}_3]^+[ArPH3​]+.

[1]
c.

Explain your answer in terms of electron pair repulsion theory.

[3]

Bonding Questions

  1. A Level
  2. /Chemistry
  3. /Bonding