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Bonding

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Question 4

Methylphosphine (CH3PH2\text{CH}_3\text{PH}_2CH3​PH2​) can be represented as RPH2\text{RPH}_2RPH2​ and its protonated form, the methylphosphonium ion ([CH3PH3]+[\text{CH}_3\text{PH}_3]^+[CH3​PH3​]+), can be represented as [RPH3]+[\text{RPH}_3]^+[RPH3​]+.

a.

Describe or draw the three-dimensional shapes around the phosphorus atom in RPH2\text{RPH}_2RPH2​ and in [RPH3]+[\text{RPH}_3]^+[RPH3​]+. Include any lone pairs on the phosphorus atom.

[3]
b.

State whether the H−P−H\text{H}-\text{P}-\text{H}H−P−H bond angle in RPH2\text{RPH}_2RPH2​ is greater than, the same as, or smaller than that in [RPH3]+[\text{RPH}_3]^+[RPH3​]+.

[1]
c.

Explain your answer in terms of electron pair repulsion theory.

[3]

Bonding Questions

  1. A Level
  2. /Chemistry
  3. /Bonding