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Aromatic chemistry (A-level only)

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Question 3

During the electrophilic substitution of benzene to form nitrobenzene, the active electrophile is generated in situ by reacting concentrated nitric acid and concentrated sulfuric acid according to the equation:

HNO3+2H2SO4→NO2++H3O++2HSO4− \text{HNO}_3 + 2\text{H}_2\text{SO}_4 \rightarrow \text{NO}_2^+ + \text{H}_3\text{O}^+ + 2\text{HSO}_4^- HNO3​+2H2​SO4​→NO2+​+H3​O++2HSO4−​

Which statement regarding this reaction is correct?

HNO3\text{HNO}_3HNO3​ is oxidized to the nitronium ion (NO2+\text{NO}_2^+NO2+​).

H3O+\text{H}_3\text{O}^+H3​O+ acts as the electrophile that attacks the aromatic ring.

One molecule of H2SO4\text{H}_2\text{SO}_4H2​SO4​ acts as a Brønsted-Lowry acid, while the other acts as a Brønsted-Lowry base.

HNO3\text{HNO}_3HNO3​ acts as a Brønsted-Lowry base.

Aromatic chemistry (A-level only) Questions

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