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Question 8

The ions present in ionic compounds can be identified using simple tests.

  • Some cations (positive ions) can be identified using a flame test.
  • Some anions (negative ions) can be identified by observing reactions in solutions of the compounds.

Table 1 shows the flame test colours for four cations.

Table 1

CationFlame test colour
bariumpale green
copperblue-green
potassiumlilac
thalliumpale green

Table 2 shows the results of three tests used to identify anions in solution.

Table 2

AnionDilute nitric acid addedBarium chloride solution addedBromothymol blue added
bromideno changeno changegreen
carbonateeffervescencewhite precipitateblue
hydrogensulfateno changeno changeyellow
sulfateno changewhite precipitategreen
sulfiteeffervescencewhite precipitateyellow

Use the information in the tables to answer these questions.

a.

In the tests, compound A gives a lilac flame and produces no change when barium chloride solution is added.

Suggest two possible identities for compound A.

[2]
b.

In the tests, compound B gives a pale green flame and produces a white precipitate when barium chloride solution is added.

A student concludes that compound B is barium sulfate.

Give two reasons why this conclusion may not be correct.

[2]
c.

Which additional test from Table 2 would show whether the anion in compound B is sulfate or carbonate?

[1]
d.

An aqueous solution contains either bromide ions or hydrogensulfate ions.

Using only information from the tables, explain how you could decide if the solution contains bromide or hydrogensulfate ions.

[2]

Chemical tests Questions

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