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Alcohols

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Question 13

The table below gives some data about members of a homologous series of compounds called the primary alcohols.

AlcoholMolecular formulaRelative formula massBoiling point in ∘C^\circ\text{C}∘C
ethanolC2H5OH\text{C}_2\text{H}_5\text{OH}C2​H5​OH4678
propan-1-ol6097
butan-1-olC4H9OH\text{C}_4\text{H}_9\text{OH}C4​H9​OH118
pentan-1-olC5H11OH\text{C}_5\text{H}_{11}\text{OH}C5​H11​OH88138
hexan-1-olC6H13OH\text{C}_6\text{H}_{13}\text{OH}C6​H13​OH102
heptan-1-olC7H15OH\text{C}_7\text{H}_{15}\text{OH}C7​H15​OH116176
a.

Complete the table by:

  • giving the molecular formula of propan-1-ol.
  • giving the relative formula mass of butan-1-ol.
  • suggesting the boiling point of hexan-1-ol.
[3]
b.

What does the data show about the relationship between boiling point and relative formula mass?

[1]
c.

The molecular formula of propene is C3H6\text{C}_3\text{H}_6C3​H6​. Propan-1-ol and propene belong to different homologous series. Explain how the formulae of these compounds show that they are in different series.

[2]
d.

Draw the displayed formulae for the two isomeric alcohols with the molecular formula C3H8O\text{C}_3\text{H}_8\text{O}C3​H8​O.

[2]
e.

What is the name given to compounds that have the same molecular formula but different displayed/structural formulae?

[1]
f.

Under suitable conditions, propan-1-ol can be dehydrated to form propene and water.

Write a chemical equation for this dehydration reaction.

[1]
g.

What is the name given to this type of reaction (other than dehydration)?

[1]
h.

Suggest a catalyst needed for this reaction.

[1]

Alcohols Questions

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