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2.7.1 Metallic bonding and the properties of metals

Metallic bonding

Definition

Metallic bonding

The electrostatic attraction between the positive metal ions in a giant lattice and the sea of delocalised electrons surrounding them.

Definition

Delocalised electrons

Electrons that are not held by one particular atom or bond and are free to move through a structure.

  1. In a solid metal, the atoms are packed closely together in a regular arrangement called a giant metallic lattice.
  2. Each metal atom loses its outer-shell electrons, which turns the atoms into positive ions.
  3. The electrons that have been lost do not belong to any one ion, so they become delocalised and move freely throughout the whole lattice.
  4. These delocalised electrons form a sea of electrons that surrounds the positive ions.
  5. Metallic bonding is the electrostatic attraction between the positive ions and the sea of delocalised electrons.
  6. The attraction acts in all directions, so each positive ion is held in the lattice by the electrons all around it.
  7. In magnesium, each atom gives up its two outer-shell electrons, so the lattice is made of Mg2+\text{Mg}^{2+}Mg2+ ions surrounded by a sea of delocalised electrons.

Metallic bonding: a regular lattice of positive metal ions in layers, surrounded by a sea of delocalised electrons that are free to move through the whole structure

Electrical conductivity of metals

  1. Metals are good conductors of electricity, because they contain delocalised electrons that are free to move through the lattice.
  2. When a voltage is applied across a piece of metal, the delocalised electrons drift through the lattice towards the positive terminal.
  3. This flow of charged electrons through the metal is an electric current.
  4. The delocalised electrons are present whether the metal is solid or liquid, so metals conduct in both states.
  5. The positive ions stay in their places in the lattice and do not carry the current.

Malleability and ductility

Definition

Malleable

Able to be hammered or pressed into a new shape without breaking.

Definition

Ductile

Able to be drawn out into thin wires without breaking.

  1. The positive ions in a metal lattice are arranged in layers.
  2. When a force is applied to a metal, the layers of positive ions can slide over one another into new positions.
  3. The delocalised electrons move with the ions, so the metallic bonding is not broken and still holds the ions together in their new positions.
  4. Metals can therefore change shape without breaking.
    1. Metals are malleable, so they can be hammered or rolled into thin sheets, such as aluminium foil.
    2. Metals are ductile, so they can be drawn out into thin wires, such as copper wire.
  5. An ionic lattice behaves differently, because sliding a layer brings ions with the same charge next to each other, so they repel and the crystal shatters.
Example

Copper in electrical wiring

  • Copper has a giant metallic lattice of positive ions surrounded by a sea of delocalised electrons.
  • The delocalised electrons can move through the lattice and carry charge, so copper is a good conductor of electricity.
  • The layers of copper ions can slide over one another without the metallic bonding breaking, so copper is ductile and can be drawn into long, thin wires.
  • A metal used for wiring needs both properties, so copper is well suited to the job.
Common Mistake
  • Do not say that the positive ions move to carry the current in a metal, because it is the delocalised electrons that move.
  • Do not describe metallic bonding as an attraction between protons and electrons, or between atoms, because the attraction is between positive ions and delocalised electrons.
  • Do not say that bonds break when a metal is bent, because the layers slide while the metallic bonding holds them together.
Exam technique

Describing metallic bonding

  • Describe metallic bonding with all three parts: electrostatic attraction, positive ions and a sea of delocalised electrons.
  • For conductivity, say that the delocalised electrons can move through the structure and carry charge.
  • For malleability and ductility, say that the layers of ions slide over one another and the metallic bonding keeps the metal in one piece.
Self review
  • What is metallic bonding?
  • What particles carry the electric current in a metal?
  • Why can the layers in a metal slide without the metal breaking?
  • What is the difference between malleable and ductile?
  • Why does an ionic crystal shatter when its layers are forced to slide?
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2.7.1 Metallic bonding and the properties of metals Revision Guide

  1. IGCSE
  2. /Chemistry
  3. /2.7.1 Metallic bonding and the properties of metals

Revision notes for CIE IGCSE Chemistry 2.7.1 Metallic bonding and the properties of metals: explanations and worked examples.

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