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6.1.3 Representing nuclei and isotopes

Nuclear notation

Definition

Nuclear notation

A way of writing a nucleus as its chemical symbol with the mass number at the top left and the atomic number at the bottom left.

  1. A nucleus is written in nuclear notation as ZAX{}^{A}_{Z}\text{X}ZA​X.
    1. X\text{X}X is the chemical symbol of the element.
    2. AAA, written at the top left, is the mass number, which is the number of protons plus neutrons.
    3. ZZZ, written at the bottom left, is the atomic number, which is the number of protons.
  2. For example, 612C{}^{12}_{6}\text{C}612​C represents a carbon nucleus with a mass number of 121212 and an atomic number of 666.
  3. The mass number is always the larger of the two numbers, except for hydrogen-1, where both numbers are 111.
  4. The chemical symbol and the atomic number give the same information, because each element has its own atomic number.
  5. Nuclear notation and the written name carry the same information, so 614C{}^{14}_{6}\text{C}614​C and carbon-14 describe the same isotope.

Reading the notation

  1. A single symbol in nuclear notation tells you the identity, charge and mass of a nucleus.
  2. The identity of the element comes from the atomic number, ZZZ, or from the chemical symbol.
  3. The charge of the nucleus is +Z+Z+Z, because each of the ZZZ protons has a relative charge of +1+1+1.
  4. The mass of the nucleus is given by the mass number, AAA, because each nucleon has a relative mass of 111.
  5. The number of neutrons, NNN, is found by subtracting the atomic number from the mass number, so N=A−ZN = A - ZN=A−Z.
  6. A neutral atom of the element has ZZZ electrons, so that their charge balances the charge of the nucleus.
  7. For 1123Na{}^{23}_{11}\text{Na}1123​Na, the nucleus has 111111 protons, a charge of +11+11+11, a mass number of 232323 and 23−11=1223 - 11 = 1223−11=12 neutrons.

Comparing isotopes

  1. Isotopes of an element have the same bottom number but a different top number in nuclear notation.
  2. Oxygen has three stable isotopes, 816O{}^{16}_{8}\text{O}816​O, 817O{}^{17}_{8}\text{O}817​O and 818O{}^{18}_{8}\text{O}818​O, which contain 888, 999 and 101010 neutrons.
  3. The uranium isotopes 92235U{}^{235}_{92}\text{U}92235​U and 92238U{}^{238}_{92}\text{U}92238​U both have 929292 protons, but they contain 143143143 and 146146146 neutrons.
  4. The difference between the mass numbers of two isotopes is equal to the difference in their numbers of neutrons.
  5. Two nuclei with the same mass number but different atomic numbers are not isotopes, because they belong to different elements.
  6. For example, 614C{}^{14}_{6}\text{C}614​C and 714N{}^{14}_{7}\text{N}714​N have the same mass number but different numbers of protons, so they are nuclei of carbon and nitrogen.
Example

Comparing two chlorine nuclei

  • Chlorine has two common isotopes, 1735Cl{}^{35}_{17}\text{Cl}1735​Cl and 1737Cl{}^{37}_{17}\text{Cl}1737​Cl.
  • Both have an atomic number of 171717, so both nuclei contain 171717 protons and have a charge of +17+17+17.
  • The number of neutrons in each nucleus is found using N=A−ZN = A - ZN=A−Z.
N35=35−17=18 N_{35} = 35 - 17 = 18 N35​=35−17=18 N37=37−17=20 N_{37} = 37 - 17 = 20 N37​=37−17=20
  • The chlorine-37 nucleus has two more neutrons, so its mass is greater by a relative mass of 222, while its charge is the same.
Common Mistake
  • Do not swap the two numbers, because the mass number is at the top and the atomic number is at the bottom.
  • Do not give the mass number as the number of neutrons, because you must subtract the number of protons first.
  • Do not call two nuclei isotopes just because they have the same mass number, because isotopes must have the same atomic number.
Exam technique

Working from nuclear notation

  • Write the subtraction A−ZA - ZA−Z when you find the number of neutrons, because a correct method can earn credit even if the final number is wrong.
  • To decide whether two nuclei are isotopes, compare the bottom numbers first, and only then the top numbers.
  • When asked to compare isotopes, state what is the same (protons and charge) and what is different (neutrons and mass).
Self review
  • In the notation ZAX{}^{A}_{Z}\text{X}ZA​X, what do AAA and ZZZ stand for?
  • How many neutrons are there in a 1327Al{}^{27}_{13}\text{Al}1327​Al nucleus?
  • What is the charge of a 2040Ca{}^{40}_{20}\text{Ca}2040​Ca nucleus?
  • How can you tell from nuclear notation that two nuclei are isotopes?
  • Why are 614C{}^{14}_{6}\text{C}614​C and 714N{}^{14}_{7}\text{N}714​N not isotopes of each other?
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