Nuclear notation
Definition
Nuclear notation
A way of writing a nucleus as its chemical symbol with the mass number at the top left and the atomic number at the bottom left.
- A nucleus is written in nuclear notation as ZAX{}^{A}_{Z}\text{X}ZAX.
- X\text{X}X is the chemical symbol of the element.
- AAA, written at the top left, is the mass number, which is the number of protons plus neutrons.
- ZZZ, written at the bottom left, is the atomic number, which is the number of protons.
- For example, 612C{}^{12}_{6}\text{C}612C represents a carbon nucleus with a mass number of 121212 and an atomic number of 666.
- The mass number is always the larger of the two numbers, except for hydrogen-1, where both numbers are 111.
- The chemical symbol and the atomic number give the same information, because each element has its own atomic number.
- Nuclear notation and the written name carry the same information, so 614C{}^{14}_{6}\text{C}614C and carbon-14 describe the same isotope.
Reading the notation
- A single symbol in nuclear notation tells you the identity, charge and mass of a nucleus.
- The identity of the element comes from the atomic number, ZZZ, or from the chemical symbol.
- The charge of the nucleus is +Z+Z+Z, because each of the ZZZ protons has a relative charge of +1+1+1.
- The mass of the nucleus is given by the mass number, AAA, because each nucleon has a relative mass of 111.
- The number of neutrons, NNN, is found by subtracting the atomic number from the mass number, so N=A−ZN = A - ZN=A−Z.
- A neutral atom of the element has ZZZ electrons, so that their charge balances the charge of the nucleus.
- For 1123Na{}^{23}_{11}\text{Na}1123Na, the nucleus has 111111 protons, a charge of +11+11+11, a mass number of 232323 and 23−11=1223 - 11 = 1223−11=12 neutrons.
Comparing isotopes
- Isotopes of an element have the same bottom number but a different top number in nuclear notation.
- Oxygen has three stable isotopes, 816O{}^{16}_{8}\text{O}816O, 817O{}^{17}_{8}\text{O}817O and 818O{}^{18}_{8}\text{O}818O, which contain 888, 999 and 101010 neutrons.
- The uranium isotopes 92235U{}^{235}_{92}\text{U}92235U and 92238U{}^{238}_{92}\text{U}92238U both have 929292 protons, but they contain 143143143 and 146146146 neutrons.
- The difference between the mass numbers of two isotopes is equal to the difference in their numbers of neutrons.
- Two nuclei with the same mass number but different atomic numbers are not isotopes, because they belong to different elements.
- For example, 614C{}^{14}_{6}\text{C}614C and 714N{}^{14}_{7}\text{N}714N have the same mass number but different numbers of protons, so they are nuclei of carbon and nitrogen.
Example
Comparing two chlorine nuclei
- Chlorine has two common isotopes, 1735Cl{}^{35}_{17}\text{Cl}1735Cl and 1737Cl{}^{37}_{17}\text{Cl}1737Cl.
- Both have an atomic number of 171717, so both nuclei contain 171717 protons and have a charge of +17+17+17.
- The number of neutrons in each nucleus is found using N=A−ZN = A - ZN=A−Z.
- The chlorine-37 nucleus has two more neutrons, so its mass is greater by a relative mass of 222, while its charge is the same.
Common Mistake
- Do not swap the two numbers, because the mass number is at the top and the atomic number is at the bottom.
- Do not give the mass number as the number of neutrons, because you must subtract the number of protons first.
- Do not call two nuclei isotopes just because they have the same mass number, because isotopes must have the same atomic number.
Exam technique
Working from nuclear notation
- Write the subtraction A−ZA - ZA−Z when you find the number of neutrons, because a correct method can earn credit even if the final number is wrong.
- To decide whether two nuclei are isotopes, compare the bottom numbers first, and only then the top numbers.
- When asked to compare isotopes, state what is the same (protons and charge) and what is different (neutrons and mass).
Self review
- In the notation ZAX{}^{A}_{Z}\text{X}ZAX, what do AAA and ZZZ stand for?
- How many neutrons are there in a 1327Al{}^{27}_{13}\text{Al}1327Al nucleus?
- What is the charge of a 2040Ca{}^{40}_{20}\text{Ca}2040Ca nucleus?
- How can you tell from nuclear notation that two nuclei are isotopes?
- Why are 614C{}^{14}_{6}\text{C}614C and 714N{}^{14}_{7}\text{N}714N not isotopes of each other?