Energy changes and frequency
Definition
Electromagnetic spectrum
The continuous range of electromagnetic waves, arranged in order of wavelength or frequency.
- Atoms and nuclei can both absorb and emit electromagnetic radiation when their energy changes.
- In an atom, the energy changes when an electron moves between energy levels.
- In a nucleus, the energy changes when the nucleus rearranges itself, for example after a radioactive decay.
- The size of the energy change decides the frequency of the radiation that is emitted or absorbed.
- A small energy change gives radiation of low frequency, and a large energy change gives radiation of high frequency.
- Different changes involve very different amounts of energy, so together they produce radiation across a wide range of frequencies in the electromagnetic spectrum.
- In order of increasing frequency, the spectrum runs from radio waves through microwaves, infrared, visible light, ultraviolet and X-rays to gamma rays.
Radiation from electrons
- Changes involving the outer electrons of an atom involve fairly small amounts of energy.
- These changes emit or absorb infrared, visible light or ultraviolet radiation.
- The coloured light from a neon sign and the orange glow of a sodium street lamp come from outer electrons falling to lower energy levels.
- Inside a fluorescent tube, mercury atoms emit ultraviolet radiation, which a coating on the glass absorbs and re-emits as visible light.
- Changes involving the inner electrons of large atoms, which are held very tightly close to the nucleus, involve much larger amounts of energy.
- These inner-electron changes emit X-rays, which is how an X-ray tube produces X-rays when fast electrons strike a metal target such as tungsten.
Radiation from nuclei
- The energy changes inside a nucleus are far larger than those involving electrons.
- A nucleus that is left with excess energy loses it by emitting a gamma ray, the highest-frequency radiation in the spectrum.
- Gamma rays therefore come from changes in the nucleus, while X-rays come from changes in the electrons.
- X-rays and gamma rays can have overlapping frequencies, so they are told apart by where they come from rather than by their frequency alone.
Absorbing radiation
- Atoms and nuclei can absorb radiation as well as emit it, when the radiation supplies the right amount of energy for a change.
- An atom absorbs radiation of the frequencies that match the energy gaps between its electron levels, which are the same frequencies it emits.
- Cool sodium vapour absorbs the same yellow-orange light that hot sodium vapour emits.
- Dense materials such as bone contain atoms whose inner electrons absorb X-rays strongly, which is why bones show up clearly on an X-ray image.
- Nuclei can also absorb gamma rays of the right energy, which moves the nucleus into a higher energy state.
Key Idea
Where each radiation comes from
- Infrared, visible light and ultraviolet: small energy changes of the outer electrons in atoms.
- X-rays: large energy changes of the inner electrons in large atoms.
- Gamma rays: very large energy changes inside the nucleus.
Common Mistake
- Do not say that gamma rays are emitted by electrons, because gamma rays come from the nucleus.
- Do not say that atoms can only give out visible light, because changes in atoms and nuclei produce radiation across the whole electromagnetic spectrum.
- Do not link a large energy change with a low frequency, because a larger energy change always gives a higher frequency.
Exam technique
Linking changes to radiation
- Name the part of the atom that changes, either the electrons or the nucleus, because the source decides the type of radiation.
- Link the size of the energy change to the frequency of the radiation in your answer.
- When asked which part of the electromagnetic spectrum a nucleus emits, the expected answer is gamma rays.
Self review
- What decides the frequency of the radiation emitted when an atom changes its energy?
- Which parts of the electromagnetic spectrum are produced by changes in the outer electrons of atoms?
- What kind of change produces X-rays?
- Which radiation is produced by energy changes in the nucleus?
- Why does bone absorb X-rays more strongly than soft tissue?