Gases can be compressed
Definition
Compression of a gas
Compression of a gas is a decrease in the volume of a gas caused by an increase in the pressure acting on it.
- The particles of a gas are widely separated, so most of the space a gas occupies is empty.
- That empty space can be taken away, which is why a gas can be squeezed into a much smaller volume.
- Pushing a piston inwards increases the pressure applied to the trapped gas, so the gas is compressed into a smaller volume.
- The compression continues until the pressure of the gas has risen enough to balance the pressure being applied to it.
- The number of particles does not change while a gas is compressed, so the same particles are simply packed closer together.
- Solids and liquids can barely be compressed at all, because their particles are already in contact and there is almost no space to remove.
- This difference is put to work in machinery, because compressed air can be stored in a cylinder and released to drive a tool, while hydraulic systems rely on a liquid that will not compress.
- A diver's cylinder is another example, holding a large mass of air in a small volume because the air inside has been compressed to a high pressure.
Gases can be expanded
Definition
Expansion of a gas
Expansion of a gas is an increase in the volume of a gas caused by a decrease in the pressure acting on it.
- Reducing the pressure acting on a gas allows it to expand into a larger volume.
- Pulling the plunger of a sealed syringe outwards lowers the pressure inside, and the trapped gas expands to fill the extra space.
- The expansion continues until the pressure of the gas has fallen enough to balance the reduced pressure pushing in on it.
- A weather balloon swells as it climbs, because atmospheric pressure falls with height and so the gas inside meets less opposition.
- A gas has no volume of its own, so its volume is set by the pressure acting on it and by the container holding it.
- The number of particles is again unchanged, so an expanded gas is the same gas with its particles spread further apart.
- Compression and expansion are opposite processes, and a gas can be taken back and forth between them by raising and lowering the pressure applied to it.
Pressure acts at right angles
Definition
Normal to a surface
A normal to a surface is a line drawn at right angles to that surface at the point being considered.
- Gas particles reach a surface from every direction, because their motion inside the container is random.
- For every particle striking the surface at an angle from one side, another arrives at a matching angle from the other side.
- The sideways effects of all those collisions therefore cancel out on average, leaving no overall push along the surface.
- What remains is a net force at right angles to the surface, in other words along the normal to it.
- This holds for every surface the gas touches, whatever the angle at which that surface is set.
- On a curved surface the direction of the net force changes from point to point, staying perpendicular to the surface at each point.
- An inflated balloon shows this clearly, since the gas pushes outwards over the whole of the inner surface and the balloon settles into a rounded shape.
- The size of that outward force grows with the area of the surface, so a large flat panel in a pressurised container carries a very large total force.
Example
Compressing air in a sealed syringe
- A syringe with its nozzle sealed holds air at atmospheric pressure, with the plunger resting at the 20 cm320\ \text{cm}^{3}20 cm3 mark.
- Pressing the plunger inwards applies a greater pressure to the trapped air.
- The air is compressed and the plunger comes to rest at the 12 cm312\ \text{cm}^{3}12 cm3 mark, where the pressure of the air balances the pressure being applied.
- No air has entered or left, so the same particles now occupy a volume that is smaller by 8 cm38\ \text{cm}^{3}8 cm3.
- Releasing the plunger removes the extra applied pressure, so the trapped air expands and pushes the plunger back out towards the 20 cm320\ \text{cm}^{3}20 cm3 mark.
- The trapped air pushes on the face of the plunger at right angles to it, which is why the plunger travels straight along the barrel rather than jamming to one side.
Exam technique
Answering compression questions
- Refer to the empty space between the particles when explaining why a gas can be compressed, since that is the reason a gas differs from a liquid.
- State clearly that the number of particles stays the same, because answers often drift into suggesting gas has been added or lost.
- Use the words at right angles to the surface or along the normal, because outwards on its own is too vague for the mark.
- Explain the right angle using the cancelling of the sideways collisions, which is the step that turns a description into an explanation.
- Draw force arrows perpendicular to the surface, and space them evenly around a curved container rather than pointing them all one way.
Common Mistake
- Do not write that the particles themselves get smaller when a gas is compressed, because only the spaces between them shrink.
- Do not write that a liquid can be compressed like a gas, because its particles are already touching.
- Do not draw the force from a gas at a slant to the surface, because the net force is always perpendicular to it.
- Do not describe the force as acting on one wall only, because a gas pushes on every surface it is in contact with.
Self review
- Explain why a gas can be compressed but a liquid cannot.
- Describe what happens to the volume of a gas when the pressure applied to it is reduced.
- Explain why a weather balloon expands as it rises through the atmosphere.
- State the direction of the net force that a gas exerts on a surface.
- Explain why the sideways effects of gas particle collisions cancel out.
- Explain why an inflated balloon takes a rounded shape.