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4.1.2 Properties of the transition metals

Transition metals are hard, strong and dense

Definition

Transition metal

A metal in the central block of the Periodic Table, between Group 2 and Group 3.

  1. Transition metals such as iron, copper, nickel and chromium sit in the central block, between Groups 2 and 3.
  2. Like other metals they are shiny, conduct electricity and heat, and can be hammered into shape.
  3. Most have high melting points, so iron melts at 1538 ∘C1538\ ^{\circ}\text{C}1538 ∘C while sodium melts at 98 ∘C98\ ^{\circ}\text{C}98 ∘C.
  4. Most have high densities, so copper has a density of 8.96 g/cm38.96\,\text{g/cm}^38.96g/cm3 while potassium has a density of 0.86 g/cm30.86\,\text{g/cm}^30.86g/cm3.
  5. They are hard and strong, which is why iron, in the form of steel, is used for bridges, girders and car bodies.
    1. The Group 1 metals, by contrast, are soft enough to cut with a knife.
Note

Mercury is a transition metal that is liquid at room temperature, so these properties describe most transition metals rather than every one.

Transition metals are less reactive than Group 1

Definition

Reactivity

How readily an element takes part in chemical reactions.

  1. Transition metals react very slowly or not at all with cold water, while every Group 1 metal reacts with cold water and releases hydrogen.
    1. Iron rusts only slowly, over days or weeks, when it is in contact with both water and oxygen.
  2. Copper does not react with water or with dilute acids, so it is used for water pipes and hot water tanks.
  3. Gold and silver are so unreactive that they stay shiny for centuries, which suits jewellery and coins.
  4. Transition metal atoms form positive ions less readily than Group 1 atoms, which is why they react less vigorously.
Example

A piece of potassium dropped into water melts and bursts into flame within seconds, while an iron nail left in water takes days to show the first signs of rust.

Many transition metals form ions with different charges

Definition

Ion

An atom or group of atoms that carries an overall electric charge.

  1. A Group 1 metal always forms ions with a 1+1+1+ charge, but many transition metals form more than one positive ion.
    1. Iron forms both iron(II) ions, Fe2+\text{Fe}^{2+}Fe2+, and iron(III) ions, Fe3+\text{Fe}^{3+}Fe3+.
    2. Copper forms both copper(I) ions, Cu+\text{Cu}^{+}Cu+, and copper(II) ions, Cu2+\text{Cu}^{2+}Cu2+.
  2. The Roman numeral in the name of a compound gives the charge on the metal ion.
  3. Different charges give different formulae, so iron(II) chloride is FeCl2\text{FeCl}_2FeCl2​ and iron(III) chloride is FeCl3\text{FeCl}_3FeCl3​.
    1. Compounds of the same metal with different ion charges have different properties, including different colours.
Common Mistake

Do not leave out the Roman numeral when naming a transition metal compound, because 'iron chloride' could mean either FeCl2\text{FeCl}_2FeCl2​ or FeCl3\text{FeCl}_3FeCl3​.

Many transition metal compounds are coloured

  1. Compounds of Group 1 metals, such as sodium chloride, are white solids that dissolve to give colourless solutions.
  2. Many transition metal compounds are coloured, both as solids and in solution.
    1. Copper(II) sulfate solution is blue, iron(II) sulfate solution is pale green and iron(III) chloride solution is orange-brown.
    2. Potassium manganate(VII) contains manganese and forms a deep purple solution.
  3. The colour depends on the ion charge, which is why iron(II) and iron(III) compounds have different colours.
  4. The colours help in identifying ions, because each of these metal ions gives a precipitate of its own colour with sodium hydroxide solution.
Note

Not every transition metal compound is coloured, since anhydrous copper(II) sulfate is a white powder that turns blue when water is added.

Transition metals and their compounds are useful catalysts

Definition

Catalyst

A substance that increases the rate of a reaction by providing an alternative pathway with a lower activation energy without being used up.

  1. Many transition metals and their compounds speed up reactions without being used up, so a small amount can be used again and again.
  2. Iron is the catalyst in the Haber process, which makes ammonia for fertilisers: N2(g)+3H2(g)⇌2NH3(g)\text{N}_2\text{(g)} + 3\text{H}_2\text{(g)} \rightleftharpoons 2\text{NH}_3\text{(g)}N2​(g)+3H2​(g)⇌2NH3​(g)
  3. Nickel catalyses the reaction of vegetable oils with hydrogen to make margarine.
  4. Manganese(IV) oxide catalyses the decomposition of hydrogen peroxide: 2H2O2(aq)→2H2O(l)+O2(g)2\text{H}_2\text{O}_2\text{(aq)} \rightarrow 2\text{H}_2\text{O(l)} + \text{O}_2\text{(g)}2H2​O2​(aq)→2H2​O(l)+O2​(g)
  5. Platinum and rhodium in car catalytic converters speed up reactions that remove carbon monoxide and nitrogen oxides from exhaust gases.
Exam technique
  • When a question asks for a property of transition metals, give the property with a named example, such as iron(II) and iron(III) ions for different charges or blue copper(II) sulfate for coloured compounds.
  • When it asks you to compare with Group 1, make each point a direct comparison, for example that iron is denser than sodium and melts at a higher temperature.
Self review
  • How do the melting point and density of iron compare with those of sodium?
  • Why is copper used for water pipes?
  • What are the formulae of iron(II) chloride and iron(III) chloride?
  • What colour is copper(II) sulfate solution?
  • Name a transition metal catalyst and the process it speeds up.
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Transition metals are d-block elements found mainly in Groups 3–12 of the Periodic Table, between the Group 2 and Group 13 blocks. Group 12 elements such as zinc, cadmium and mercury are d-block metals but are generally not classified as transition metals because their atoms and common ions have full d subshells. Examples of transition metals include iron, copper, nickel and chromium.

Like other metals, they conduct heat and electricity, are shiny and can be hammered into shape. Most transition metals are also hard, strong and dense, with high melting points.

For example, iron melts at 1538 ∘C1538\,^{\circ}\text{C}1538∘C compared with 98 ∘C98\,^{\circ}\text{C}98∘C for sodium. Copper has a density of 8.96 g/cm38.96\,\text{g/cm}^38.96g/cm3, compared with 0.86 g/cm30.86\,\text{g/cm}^30.86g/cm3 for potassium. Iron also acts as a catalyst in the Haber process: N2+3H2⇌2NH3\mathrm{N_2 + 3H_2 \rightleftharpoons 2NH_3}N2​+3H2​⇌2NH3​.

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Where are transition metals found in the Periodic Table?

4.1.2 Properties of the transition metals Revision Guide

  1. GCSE
  2. /Chemistry
  3. /4.1.2 Properties of the transition metals

Revision notes for OCR GCSE Chemistry 4.1.2 Properties of the transition metals: explanations and worked examples.

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