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6.3.4 Producing potable water

Potable water is safe but not pure

Definition

Potable water

Water that is safe to drink.

  1. Potable water can contain dissolved salts and microorganisms, as long as their levels are low enough to be safe.
    1. It therefore contains more than one substance, so it is not pure in the chemical sense.
  2. In the UK, most drinking water comes from fresh water in rivers, lakes and reservoirs, or from ground water stored in rocks.
  3. Where fresh water is scarce, sea water or treated waste water can be used to increase the supply.
  4. A growing population and more frequent droughts mean that more places need to use these other sources.
Common Mistake

Do not write portable water, because the word for water that is safe to drink is potable.

Four treatment stages make fresh water potable

Definition

Sedimentation

A separation method in which water is left to stand so that insoluble particles settle to the bottom.

Definition

Sterilisation

Killing the harmful microorganisms in water, for example by adding chlorine or ozone or using ultraviolet light.

  1. Screening passes the water through a mesh that removes large objects such as twigs, leaves and litter.
  2. In sedimentation tanks, the water is left to stand so that particles of sand and soil settle to the bottom.
    1. Chemicals such as aluminium sulfate can be added to make fine particles clump together and settle faster.
  3. Filtration through beds of sand and gravel removes the remaining small insoluble particles.
    1. Filtration does not remove dissolved substances, because they pass through the filter with the water.
  4. Chlorine is added to kill harmful microorganisms, although ozone or ultraviolet light can be used instead.
Key Idea

Screening, sedimentation and filtration all separate insoluble materials from the water, while sterilisation kills microorganisms instead of separating anything.

Distillation removes dissolved salts from sea water

Definition

Desalination

Removal of dissolved salts from sea water to produce water that is fit to drink.

Definition

Distillate

The liquid collected after vapour has been condensed during distillation.

  1. Sea water contains about 35 g of dissolved salts, mainly sodium chloride, in every kilogram, which is far too salty to drink.
  2. Sedimentation and filtration cannot remove these salts, because dissolved ions pass through filters.
  3. In distillation, sea water is heated so that the water boils off as vapour and the salts stay behind.
    1. The vapour is cooled in a condenser, and the liquid water collected is pure.
  4. Boiling large volumes of water needs a lot of energy, so distillation is expensive and is used mainly where fuel is cheap and fresh water is scarce, as in parts of the Middle East.
  5. Distilled water tastes flat, so small amounts of minerals are added back before it is supplied.
Practical
  • Aim: produce pure water from salty water and check that it is pure.
  • Apparatus: a round-bottomed flask, anti-bumping granules, a thermometer from 000 to 110 ∘C110\ ^{\circ}\text{C}110 ∘C, a still head with a side arm, a Liebig condenser with rubber tubing, a collecting beaker, a Bunsen burner or heating mantle, clamps and stands, salty water and two watch glasses.

Method

  • Half-fill the round-bottomed flask with salty water and add a few anti-bumping granules.
  • Fit the thermometer with its bulb level with the side arm.
  • Connect the side arm to the condenser, with cold water entering at the bottom and leaving at the top.
  • Heat gently and collect the distillate in the beaker, checking that the thermometer reads about 100 ∘C100\ ^{\circ}\text{C}100 ∘C while water distils over.
  • Stop heating before the flask boils dry.
  • Evaporate a few drops of the distillate on one watch glass and a few drops of the salty water on the other.

Accuracy and safety

  • The distillate is pure water if it boils at 100 ∘C100\ ^{\circ}\text{C}100 ∘C and leaves no solid on the watch glass.
  • The salty water leaves a white solid, which shows the difference.
  • Never heat a closed system, so check that the end of the condenser is open to the air.
  • Wear eye protection and let the apparatus cool before taking it apart.

Reverse osmosis holds back dissolved salts

Definition

Reverse osmosis

A method of desalination in which salty water is forced at high pressure through a membrane that lets water molecules through but holds back dissolved ions.

  1. Sea water is first filtered to remove sand and other insoluble particles.
  2. It is then pumped at high pressure against a partially permeable membrane.
    1. The membrane lets water molecules through but stops most of the dissolved ions.
  3. The very salty water left behind, called brine, is returned to the sea.
  4. Reverse osmosis uses less energy than distillation, because the water does not have to be boiled.
    1. The pumps still need energy, and the membranes are expensive and need regular cleaning and replacement.
Example

Thames Water's desalination plant at Beckton in east London uses reverse osmosis to make drinking water from salty water taken from the tidal River Thames.

Treating waste water to supply potable water

  1. Waste water from homes, farms and industry contains organic matter, harmful microorganisms and sometimes harmful chemicals.
  2. Screening removes large objects and grit, as it does for fresh water.
  3. Sedimentation then separates the waste into solid sludge, which settles, and a liquid layer above it.
  4. Bacteria break down the organic matter left in the liquid, and further filtration removes fine particles.
  5. The water is sterilised before it is returned to rivers or, after more treatment, reused as potable water.
  6. Treating waste water to drinking standard takes more processing than treating fresh water, so it is used mainly where water is scarce.
Exam technique

When a question asks how a method makes water potable, name the separation technique and say what it removes, for example that filtration removes insoluble particles but not dissolved salts.

Self review
  • What does potable water mean, and why is it not pure?
  • What does sedimentation remove from fresh water?
  • Why is chlorine added to drinking water?
  • Why can filtration not produce potable water from sea water?
  • Why does reverse osmosis use less energy than distillation?
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Potable water is water that is safe to drink. It can contain dissolved salts and microorganisms, provided their levels are low enough to be safe.

A pure substance contains only one substance, so chemically pure water contains only water. Potable water usually contains dissolved substances, so it is a mixture.

In the UK, most drinking water comes from rivers, lakes, reservoirs and groundwater stored in rocks. Where fresh water is scarce, sea water and treated waste water can provide additional supplies.

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Why can potable water be safe to drink without being chemically pure?

6.3.4 Producing potable water Revision Guide

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Revision notes for OCR GCSE Chemistry 6.3.4 Producing potable water: explanations and worked examples.

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